N-t-butylbenzaldimine; NOPF6 in tetrahydrofuran soln. of benzaldehyde t-butylimine in THF added dropwise to NOPF6, Mn complex in THF added dropwise, stirred at room temp. for 45 min; not isolated; detected by IR;
参考文献
Fjare, Douglas E.; Keyes, David G.; Gladfelter, Wayne L.
Journal of Organometallic Chemistry, 1983 , vol. 250, # 1 p. 383 - 394
in diethyl ether byproducts: 1,2,4,5-tetraphenylbenzene; soln. of Mn-complex in Et2O was stirred overnight at 20°C, evapd. to dryness; residue was chromd. on silica gel/hexane column, eluted with hexane; detd. by IR;
参考文献
Desimone,D.M.; Desrosiers,P.J.; Hughes,R.
Journal of the American Chemical Society, 1982 , vol. 104, p. 4842
in tetrahydrofuran byproducts: CH3CN; addn. of 5 mL of 1E-2 M Mn(CO)5(1-) in THF to 5 mL of 1E-2 M Mn(CO)5(MeCN)(1+) in THF under Ar at 22°C, react. time <5 min; not isolated; monitored by IR;
参考文献
Lee, K. Y.; Kuchynka, D. J.; Kochi, J. K.
Organometallics, 1987 , vol. 6, p. 1886 - 1897
bis(η4-1,5-cyclooctadiene)nickel(0) in tetrahydrofuran under Ar to a soln. of Mn-complex in THF, Ni-complex was added, stirredat 22°C for 22 h; evapd., extd. with hexane, filtered, crystd.;
参考文献
VanDerveer, Michael C.; Burlitch, James M.
Journal of Organometallic Chemistry, 1980 , vol. 197, # 3 p. 357 - 368
