反应条件
in tetrahydrofuran byproducts: NaBr, CO; high-vac. or inert-atm. techniques; addn. of THF by vac.-distn. to Mn-complex, warmed to room temp., dropwise addn. of B-compound in THF (via syringe), within 30 min soln. darkened to red, stirred (8 h), opened to air; filtration, evapn., preparative TLC (silica gel, hexane), two bands: bright yellow: Mn2-complex; bright red-orange: sublimation onto a 0°C cold finger under vac.; elem. anal.;
参考文献
Plumb, Carole A.; Carroll, Patrick J.; Sneddon, Larry G.
Organometallics, 1992 , vol. 11, p. 1665 - 1671
