反应条件
KOH in diethyl ether; dichloromethane byproducts: AgBr; Ar-atmosphere; in dark; stirring of Mn-complex and AgClO4 in CH2Cl2 (2.5 h), filtration off of AgBr, solvent removal (vac.), addn. of HCCPh andKOH in Et2O (-70°C), stirring, warming to 10°C during 6 h; solvent removal (vac.), extn. (hexane), chromy. (SiO2, hexane, then CH2Cl2/hexane=1:1), evapn.;
参考文献
Journal of Organometallic Chemistry, , vol. 293, p. 379 - 390
