in tetrahydrofuran Kinetics; byproducts: CO; under inert atmosphere, slight excess of (PPN)Mn(CO)5, stirred for 3 h, at 25°C; THF remove, extracted with hexane, IR;
in not given Irradiation (UV/VIS); irradiation of soln. of complex (Oriel mercury arc source equipped with an Osram HBO 200-W mercury lamp); radical is obtained in equil. with its dimeric species;
CO in neat (no solvent) Mn metal evapd. to reactor and condensed with cyclooctadiene at -196°C; reactor was then filled with CO to ca. 1E5 Pa and allowed to warm to room temp.; extn. (hexane), chromy. (Al2O3);
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 901 - 904
