in tetrahydrofuran byproducts: {Fe(CS)(CO)Cp}2; N2; the reaction mixture was stirred for 15 min;; solvent removal; column chromy. ( alumina, CH2Cl2:hexane=1:9) afforded Mn2(CO)10, then ((Cp)(CO)2FeMn(CO)5), then ((Cp)COFe(CO)(CS)Mn(CO4)- evapn. to dryness, recrystn. from CH2Cl2/pentane, elem. anal.;
in tetrahydrofuran (N2 or Ar), 25°C, stirring for 30 min in a round-bottom flask; solvent is removed under reduced pressure, extd. with pentane, chromy. on silica gel(CH2Cl2), determined by (55)Mn-NMR;
参考文献
Canadian Journal of Chemistry, , vol. 68, # 3 p. 492 - 501
in toluene (under inert gas by Schlenk technique); a soln. of the bicyclononatriene and the Mn-complex is heated to 80°C for 48 h, cooled to room temp.; the solvent is evapd., solid is extd., filtd., the filtrate is cooled to -30°C;
