hydrogen in methanol T=25°C; P=3150.3 Torr; 4 h; enantioselectivity of reaction dependent on various rhodium complexes with 1,2-bis(phosphanyl)pyrrolidine ligands; various conditions; also N-acetylcinnamic acid methylester; Product distribution;
hydrogen; triethylamine; lt;((R)-(1,1'-binaphthyl-2,2'-diyl)bis(diphenylphosphine))RuCl2gt;2NEt3 in tetrahydrofuran; ethanol T=35°C; P=1520 Torr; 24 h; RuHCl-bis<(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl>, with and without Et3N; Title compound not separated from byproducts;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 1571 - 1575
hydrogen; triethylamine; lt;((R)-(1,1'-binaphthyl-2,2'-diyl)bis(diphenylphosphine))RuCl2gt;2NEt3 in tetrahydrofuran; ethanol T=35°C; P=1520 Torr; 24 h; Title compound not separated from byproducts;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 1571 - 1575
potassium hydroxide; potassium phosphate buffer; porcine kidney acylase I T=40°C; relative initial rate of hydrolysis, also with Aspergillus acylase I as a catalyst; with or without CoCl2;
参考文献
Journal of the American Chemical Society, , vol. 111, # 16 p. 6354 - 6364
