双(三苯基膦)氯化铂(II)合成路线 （共 132 条）
反应条件
in xylene byproducts: Me2NH; N2-atmosphere; refluxing for 15 min; solvent removal; product mixt. not sepd., detd. by (31)P-NMR spectroscopy; further unidentified product;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 767 - 776
反应条件
in diethyl ether; benzene N2-atmosphere; product mixt. not sepd., detd. by (31)P- and (1)H-NMR spectroscopy;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 767 - 776
反应条件
in dichloromethane a soln. of complexes in CH2Cl2 was heated under reflux for 3 h; solvent was removed and benzene was added to oil, ppt. was filtered offand washed with benzene, dried in vac., filtrate was reduced to drynessand recrystd. from CH2Cl2/hexane to dive the 2-d product; IR, NMR;
参考文献
Inorganica Chimica Acta, , vol. 103, p. 83 - 94
反应条件
byproducts: 1-pentene; 293 K;
参考文献
Organometallics, , vol. 10, p. 4036 - 4045
反应条件
in benzene according to R. Bender, P. Braunstein, A. Tiripicchio and C. M. Tiripicchio, J. Chem. Soc., Chem. Commun., 42 (1984); CO atm.; mixture stirred (4 h); homogenization step; after 15 min yellow ppt.;; washing (benzene/hexane); dried in vac.;;
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 36, p. 2360 - 2362,2188 - 2190
反应条件
in chloroform-d1 (N2, Schlenk technique); reaction of platinum compd. and 1 equiv. of phosphine deriv. in CDCl3; NMR;
参考文献
Dalton Transactions, , vol. 40, # 11 p. 2588 - 2600
反应条件
in chloroform-d1 Kinetics; byproducts: DMSO, Cl(1-), triphenylphosphine oxide; addn. of PPh3 (2 equiv.) to soln. of Pt(OC4H8NCSNCOC6H5)Cl(DMSO) (1 equiv.) in CDCl3 in NMR tube, vigorously shaking; not isolated, detected by NMR;
参考文献
Journal of the Chemical Society, Dalton Transactions, , # 24 p. 4579 - 4586
反应条件
in chloroform-d1 byproducts: DMSO, Cl(1-); addn. of PPh3 (2 equiv.) to soln. of Pt(OC4H8NCSNCOOC6H9(CH3)((CH3)2CH))Cl(DMSO) (1 equiv.) in CDCl3 in NMR tube, vigorously shaking; not isolated, detected by NMR;
参考文献
Journal of the Chemical Society, Dalton Transactions, , # 24 p. 4579 - 4586
反应条件
in dimethylsulfoxide-d6 (N2, Schlenk technique); reaction of platinum compd. and 1 equiv. of phosphine deriv. in DMSO-d6; NMR;
参考文献
Dalton Transactions, , vol. 40, # 11 p. 2588 - 2600
反应条件
in chloroform-d1 byproducts: DMSO, Cl(1-); addn. of PPh3 (2 equiv.) to soln. of Pt((C2H5)2NCSNCOOC6H9(CH3)((CH3)2CH))Cl(DMSO) (1 equiv.) in CDCl3 in NMR tube, vigorously shaking; not isolated, detected by NMR;
参考文献
Journal of the Chemical Society, Dalton Transactions, , # 24 p. 4579 - 4586
