双(三苯基膦)氯化铂(II)合成路线 （共 132 条）
参考文献
Journal of the Chemical Society, Dalton Transactions, , p. 2647 - 2658
反应条件
in dimethylsulfoxide-d6 (N2, Schlenk technique); reaction of platinum compd. and 1 equiv. of phosphine deriv. in presence of 6 equiv. of tetrabutylammonium chloride in DMSO-d6; NMR;
参考文献
Dalton Transactions, , vol. 40, # 11 p. 2588 - 2600
反应条件
in dichloromethane T=20 - 25°C; 0.5 h; Glovebox;
参考文献
Kuniyasu, Hitoshi; Sanagawa, Atsushi; Nakane, Daisuke; Iwasaki, Takanori; Kambe, Nobuaki; Bobuatong, Karan; Lu, Yunpeng; Ehara, Masahiro
Organometallics, 2013 , vol. 32, # 6 p. 2026 - 2032
反应条件
1: acetonitrile; dichloromethane; methanol 2: dichloromethane; methanol View Scheme
参考文献
Polyhedron, , vol. 26, # 16 p. 4737 - 4745
反应条件
1: acetonitrile; dichloromethane; methanol 2: dichloromethane; methanol View Scheme
参考文献
Polyhedron, , vol. 26, # 16 p. 4737 - 4745
反应条件
oxygen in acetonitrile; benzene Electrolysis; dissolving cis-(PtCl2(PPh3)2) in preelectrolyzed acetonitrile/benzene (5/2 v/v, containing 0.1 M TBAP, under N2), electrolysis to zero current at -1.60 V (2 - 3 h, Ar-atmosphere, room temp.), bubbling O2 through soln. (30 min, room temp.); evapg. (in vacuo), extg. (benzene), filtering, concg.;
参考文献
Davies, Julian A.; Eagle, Cassandra T.; Otis, Deborah E.; Venkataraman, Uma
Organometallics, 1989 , vol. 8, p. 1080 - 1088
反应条件
in 1,2-dichloro-ethane < 20 min at room temp.; detn. by IR-spectroscopy;
参考文献
Organometallics, , vol. 4, p. 268 - 274
反应条件
sodium tetrahydroborate in ethanol heated at 60°C and 40 bar in autoclave for 4 h; filtered, washed (H2O, EtOH, pentane), elem. anal.;
参考文献
Chemische Berichte, , vol. 115, # 5 p. 1998 - 1999
反应条件
in ethanol bubbling ethene into stirred soln. of Pt-complex in EtOH to saturation (under N2), slow addn. of B-compd., bubbling ethene (2 h); filtration, washing (H2O, EtOH), drying in air;
参考文献
Journal of Organometallic Chemistry, , vol. 388, # 1+2 p. 215 - 220
反应条件
pyridine in hexane to Pt complex and pyridine in benzene soln. thiophenol in benzene was added dropwise and stirred for 2 h; soln. was filtered, hexane was added, ppt. was filtered, washed with benzebe and dried in vacuo, purification by PTLC (benzene); elem. anal.;
参考文献
Yamashita, Fumikazu; Kuniyasu, Hitoshi; Terao, Jun; Kambe, Nobuaki
Inorganic Chemistry, 2006 , vol. 45, # 3 p. 1399 - 1404
