双(三苯基膦)氯化铂(II)合成路线 （共 132 条）
反应条件
1: NaOH / water; benzene 2: S=P(C6H4-4-Me)3 / benzene-d6 View Scheme
参考文献
Yamashita, Fumikazu; Kuniyasu, Hitoshi; Terao, Jun; Kambe, Nobuaki
Inorganic Chemistry, 2006 , vol. 45, # 3 p. 1399 - 1404
反应条件
1: triethylamine / toluene; diethyl ether 2: S=P(C6H4-4-Me)3 / benzene-d6 View Scheme
参考文献
Yamashita, Fumikazu; Kuniyasu, Hitoshi; Terao, Jun; Kambe, Nobuaki
Inorganic Chemistry, 2006 , vol. 45, # 3 p. 1399 - 1404
反应条件
sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate; triphenylphosphine in tetrahydrofuran byproducts: NaCl, HCl, (C6H5)3PO; stirred at 25°C for 24 h; aq. layer removed, org. layer evaporated at 40°C in vacuo, residue treated with abs. C2H5OH, stirred at 60°C for 20 min, filtered, kept at -15°C for 30 min, filtered (Ar), washed (cold abs. C2H5OH), dried in vacuo; IR, NMR;
参考文献
Ioele, Marcella; Ortaggi, Giancarlo; Scarsella, Marco; Sleiter, Giancarlo
Polyhedron, 1991 , vol. 10, p. 2475 - 2476
反应条件
1: acetonitrile; dichloromethane; methanol 2: dichloromethane; methanol View Scheme
参考文献
Polyhedron, , vol. 26, # 16 p. 4737 - 4745
反应条件
in not given reaction was complete in 6 h at room temp.; no other products were formed; elem. anal. for Pt-complex;
参考文献
Giolando, Dean M.; Rauchfuss, Thomas B.; Clark, George M.
Inorganic Chemistry, 1987 , vol. 26, p. 3080 - 3082
反应条件
in tetrahydrofuran under N2, mixt. of phosphorane and Pt complex in THF was stirred for 12h, pptn.; volatiles removed in vac., residue washed (10 times hexane, 10 times THF (to dissolve the η2-complex), residue (cis complex) and washing (η2.-complex) pumped dry separately, each heated to 90°C under vac., elem. anal.;
参考文献
Inorganic Chemistry, , vol. 26, p. 1926 - 1929
反应条件
in acetonitrile all manipulations using Schlenk techniques; org. compd. added to soln. of Pt compd. (in molar ratio of 3.3:1) at room temp., stirred for 24 h, equilibrium reaction; title compd. not isolated but (Pt(SCF3)3(PPh3))(1-) ion confirmed by (19)F NMR spectroscopy;
参考文献
Kirij, Natalya V.; Tyrra, Wieland; Naumann, Dieter; Pantenburg, Ingo; Yagupolskii, Yurii L.
Zeitschrift fur Anorganische und Allgemeine Chemie, 2006 , vol. 632, # 2 p. 284 - 288
反应条件
1: Na naphthalide / toluene; tetrahydrofuran
2: not given
View Scheme
参考文献
Krautscheid; Matern; Kovacs; Fritz; Pikies
Zeitschrift fur Anorganische und Allgemeine Chemie, 1997 , vol. 623, # 12 p. 1917 - 1924
反应条件
N2H4; EtOH; H2 in ethanol
byproducts: [Pt(PPh3)]n; dropwise addn. of 85percent aq. N2H4 to suspn. of Pt-complex, refluxing, filtration off of Pt(PPh3)3, bubbling H2 through filtrate; concn. (vac.), collection, washing (H2O, hexane), dissoln. in C6H6, chromy. (Al2O3, C6H6);
参考文献
Ugo, R.; Cenini, S.; Pilbrow, M. F.; Deibl, B.; Schneider, G.
Inorganica Chimica Acta, 1976 , vol. 18, p. 113 - 120
反应条件
Na naphthalide in tetrahydrofuran; toluene
byproducts: NaCl, tBu2PMe, Pt; inert atm.; equimolar ratio, cooling (-78 to 0°C), stirring (10 min), concn. (vac., 20°C), standing (12 h, 20°C); concn. (in 5 h, 20°C), washing (hexane), filtn., evapn. (toluene);
参考文献
Krautscheid; Matern; Kovacs; Fritz; Pikies
Zeitschrift fur Anorganische und Allgemeine Chemie, 1997 , vol. 623, # 12 p. 1917 - 1924
