双(三苯基膦)氯化铂(II)合成路线 （共 132 条）
反应条件
in acetonitrile; benzene
byproducts: OPPh3; Electrolysis; dissolving cis-(PtCl2(PPh3)2) in preelectrolyzed acetonitrile/benzene (5/2 v/v, containing 0.1 M TBAP, under N2), electrolysis to zero current at -1.60 V (2 - 3 h, Ar-atmosphere, room temp.); small amts. of OPPh3; evapg. (in vacuo), extg. (benzene), filtering, concg.;
参考文献
Davies, Julian A.; Eagle, Cassandra T.; Otis, Deborah E.; Venkataraman, Uma
Organometallics, 1989 , vol. 8, p. 1080 - 1088
反应条件
in not given
(argon); modest yield; elem. anal.;
参考文献
Lappert, Michael F.; Raston, Colin L.; Skelton, Brian W.; White, Allan H.
Journal of the Chemical Society - Dalton Transactions, 1997 , # 17 p. 2895 - 2902
反应条件
in tetrahydrofuran
(N2), deoxygenated and distd. solvents; react. of Pt-compd. with Fe-compd. (moler ratio 1:2) in THF at room temp. overnight; chromy. (silica gel, pentane/toluene);
参考文献
Bender, Robert; Braunstein, Pierre; Fischer, Jean; Ricard, Louis; Mitschler, Andre
Nouveau Journal de Chimie, 1981 , vol. 5, p. 81 - 84
反应条件
potassium hydroxide in methanol; benzene
to a suspn. of substituted catechol in benzene was added MeOH soln. of KOH; prepd. soln. was syringed into suspn. of Pt complex in benzene; stirring at room temp. for 3.5 h (Ar); filtration, evapn., washing with water, drying in vac., dissoln. in CH2Cl2, filtration, evapn., washing with ether, drying in vac., crystn. from ether/hexane; elem. anal.;
参考文献
Gandolfi, Ottavio; Blum, Jochanan
Inorganica Chimica Acta, 1983 , vol. 80, p. 103 - 106
反应条件
in tetrahydrofuran
under protective gas; soln. refluxed for 1 wk; Pt compound not isolated, detected by (31)P-NMR;
参考文献
Schaefer, H.; Binder, D.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1988 , vol. 560, p. 65 - 79
反应条件
in acetonitrile; benzene
byproducts: OPPh3; Electrolysis; dissolving cis-(PtCl2(PPh3)2) in preelectrolyzed acetonitrile/benzene (5/2 v/v, containing 0.1 M TBAP, under N2), electrolysis to zero current at -1.60 V (2 - 3 h, Ar-atmosphere, room temp.); small amts. of OPPh3; evapg. (in vacuo), extg. (benzene), filtering, concg.;
参考文献
Davies, Julian A.; Eagle, Cassandra T.; Otis, Deborah E.; Venkataraman, Uma
Organometallics, 1989 , vol. 8, p. 1080 - 1088
反应条件
in neat (no solvent)
sample heating in TG or DTA apparatus at 10 K/min in static or dynamic air (30 ml/min) in temp. range 25-900°C (intermediate formation intemp. range of 250-360 and 360-460°C); TG, DTA;
参考文献
Barbieri, Roberto Santos; Bellato, C. R.; Massabni, A. C.
Thermochimica Acta, 1995 , vol. 259, p. 277 - 286
反应条件
in chloroform-d1
in NMR tube; 60°C for a few h; filtered; evapn. to dryness; detn. by NMR and MS;
参考文献
Molter, Anja; Mohr, Fabian
Zeitschrift fur Anorganische und Allgemeine Chemie, 2009 , vol. 635, # 1 p. 134 - 138
反应条件
air in acetonitrile; benzene
Electrolysis; dissolving cis-(PtCl2(PPh3)2) in preelectrolyzed acetonitrile/benzene (5/2 v/v, containing 0.1 M TBAP, under N2), electrolysis to zero current at -1.60 V (2 - 3 h, Ar-atmosphere, room temp.), exposing soln. to air (1 week, room temp.);
参考文献
Davies, Julian A.; Eagle, Cassandra T.; Otis, Deborah E.; Venkataraman, Uma
Organometallics, 1989 , vol. 8, p. 1080 - 1088
反应条件
oxygen in acetonitrile; benzene
Electrolysis; dissolving cis-(PtCl2(PPh3)2) in preelectrolyzed acetonitrile/benzene (5/2 v/v, containing 0.1 M TBAP, under N2), electrolysis to zero current at -1.60 V (2 - 3 h, Ar-atmosphere, room temp.), bubbling O2 through soln. (30 min, room temp.); evapg. (in vacuo), extg. (benzene), filtering, concg.;
参考文献
Davies, Julian A.; Eagle, Cassandra T.; Otis, Deborah E.; Venkataraman, Uma
Organometallics, 1989 , vol. 8, p. 1080 - 1088
