双(三苯基膦)氯化铂(II)合成路线 （共 132 条）
反应条件
air in acetonitrile; benzene
Electrolysis; dissolving cis-(PtCl2(PPh3)2) in preelectrolyzed acetonitrile/benzene (5/2 v/v, containing 0.1 M TBAP, under N2), electrolysis to zero current at -1.60 V (2 - 3 h, Ar-atmosphere, room temp.), exposing soln. to air (30 min, room temp.); evapg. (in vacuo), extg. (benzene), filtering, concg.;
参考文献
Davies, Julian A.; Eagle, Cassandra T.; Otis, Deborah E.; Venkataraman, Uma
Organometallics, 1989 , vol. 8, p. 1080 - 1088
反应条件
carbon dioxide; oxygen in acetonitrile; benzene
Electrolysis; a MeCN-benzene soln. of Pt-complex was electrolyzed at -1.60 V vs. Ag/AgCl under Ar (Hg working electrode, Pt wire counterelectrode, n-Bu4ClO4, suspended activated Al2O3, two-electron reduction) followed by exposure to air; products were identified in soln. by (31)P NMR spectroscopy;
参考文献
Davies, Julian A.; Eagle, Cassandra T.; Otis, Deborah E.; Venkataraman, Uma
Organometallics, 1986 , vol. 5, p. 1264 - 1266
