双(三苯基膦)氯化铂(II)合成路线 （共 132 条）
反应条件
in diethyl ether condensing excess ketone onto suspn. of Pt-complex (-196°C), sealing, warming to room temp., shaking for 24 h; removal of volatiles, filtration, washing (Et2O), drying (vac.);
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 1906 - 1910
反应条件
in toluene heating (N2, 100-110°C, 6 h), standing (25°C, overnight); evapn. to small vol., addn. of Et2O (pptn.), extn. (C6H6), filtration with charcoal, evapn., pptn. with Et2O, elem. anal.;
参考文献
Journal of Organometallic Chemistry, , vol. 361, p. 255 - 268
反应条件
dichloromethane in dichloromethane byproducts: H2O, Ph3PO; a soln. of (Ph3P)2PtO2 in CH2Cl2 was kept under Ar in the dark for 15 dor in daylight for 5-10 d; solvent was removed under oil-pump vac., residue washed with 30/70 benzene-pentane, benzene, dried in vacuo and recrystd. from CHCl3 to give pure (Ph3P)2Pt(CO)3; elem. anal., before recrystn. it was contaminated with ca. 3percent of cis-(Ph3)P)2PtCl2;
参考文献
Journal of Organometallic Chemistry, , vol. 247, # 1 p. C1 - C4
反应条件
in acetonitrile condensation of excess MeCN onto Pt-complex (-78°C), warming to 25°C (stirring); filtration, pptn. on cyclopentane addn., volume reduction of filtrate, pptn. on cyclopentane addn.;
参考文献
Inorganica Chimica Acta, , vol. 36, p. 45 - 54
反应条件
1: benzene 2: benzene 3: HCl / benzene View Scheme
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 287 - 294
反应条件
in dichloromethane byproducts: PC(C6H2(C(CH3)3)3); (Ar); mixt. is stirred at room temp. for 12 h; solvent is evapd. under vacuum, residue is extd. with hexanes, filtn. (Celite), volume is reduced, crystn. at -78°C;
参考文献
Organometallics, , vol. 13, p. 2444 - 2453
反应条件
in dichloromethane reduction of solvent in vac. led to the pptn. of a mixture of cis and trans isomers, identified by their soln. 31P NMR spectra;
参考文献
Journal of the American Chemical Society, , vol. 104, # 2 p. 438 - 445
反应条件
dichloromethane in dichloromethane-d2 byproducts: H2O; a soln. of (Ph3P)2PtO2 and CH2Cl2 in CD2Cl2 was kept in the dark or in daylight for 7 d, reaction was monitored by (31)P NMR spectroscopy; (31)P NMR anal. of the reaction mixt., the presence of H2O was confirmed by (1)H NMR;
参考文献
Journal of Organometallic Chemistry, , vol. 247, # 1 p. C1 - C4
反应条件
1: benzene 2: benzene 3: benzene 4: HCl / dichloromethane View Scheme
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 287 - 294
反应条件
in dichloromethane-d2
参考文献
Organometallics, , vol. 31, # 18 p. 6652 - 6657
