双(三苯基膦)氯化铂(II)合成路线 （共 132 条）
反应条件
Sn(i-Pr)4 in dichloromethane N2-atmosphere; excess of Sn-compd., 40°C, 12 h; not isolated, detd. by (31)P-NMR spectroscopy; further unidentified products;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 134 - 138
反应条件
1: dichloromethane 2: dichloromethane View Scheme
参考文献
Organometallics, , vol. 10, p. 4036 - 4045
反应条件
1: ethanol 2: HCl / ethanol View Scheme
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 2060 - 2067
反应条件
in dichloromethane Irradiation (UV/VIS); .ltorsim. 313 nm;
参考文献
Organometallics, , vol. 4, p. 647 - 657
反应条件
in hexadeuterioacetone; acetone Pt complex mixed with 2.0 equiv of SnCl2*2H2O, solvents added, shook until clear soln. formed; not isolated, monitored by NMR;
参考文献
Inorganic Chemistry, , vol. 22, p. 434 - 438
反应条件
in acetone Pt complex reacted with 2.0 equiv of SnCl2*2H2O in Me2CO; slowly evapd. in air, cooled, sepd. cryst. product;
参考文献
Inorganic Chemistry, , vol. 22, p. 427 - 433
反应条件
in dichloromethane for 1 h at room temp.;
参考文献
Organometallics, , vol. 24, # 11 p. 2764 - 2772
反应条件
in solid mixt. of PtCl2, PPh3 and anhydrous K2CO3 ball-milled; mechanism discussed; detd. by (31)P NMR;
参考文献
Chemical Communications, , # 15 p. 1606 - 1607
反应条件
CO in dichloromethane (N2), complex weighed in NMR-tube, solvent added, cooled to 198 K, pentene added, temp. raised by intervals of 5 K until 308 K, isomerization if CO-excess added; (31)P-NMR;
参考文献
Organometallics, , vol. 10, p. 4036 - 4045
反应条件
in dichloromethane byproducts: 1-pentene; (N2), NMR-tube, cooled to 198 K, temp. raised by intervals of 5 K until 308 K; (31)P-NMR;
参考文献
Organometallics, , vol. 10, p. 4036 - 4045
