反应条件
n-butyllithium; N,N,N',N,-tetramethylethylenediamine in hexane N2-atmosphere; dropwise addn. of BuLi to mixt. of Fe-complex and TMEDA, stirring (room temp., 18 h), addn. of ether, addn. of 2 equiv. of ammonium salt, stirring (room temp., 18 h), refluxing for 10 min; dropwise addn. of H2O, stirring for 15 min, addn. of further H2O, extn. of aq. layer into ether, drying of combined org. layers (MgSO4), concn. (45°C, reduced pressure), chromy. (Al2O3, petroleum ether, ether/petroleum ether, MeOH/ether);
参考文献
Glidewell, Christopher; Royles, Brodyck J. L.; Smith, David M.
Journal of Organometallic Chemistry, 1997 , vol. 527, # 1-2 p. 259 - 261
