反应条件
carbon disulfide; ammonia in toluene
byproducts: COS, NH4Cl, HCl; N2-atmosphere; bubbling dry NH3 (ice bath, 30 min), CS2 addn. (after 10 min of bubbling, pptn.), collection, dissoln. in THF, addn. of COCl2 in toluene (acetone/dry ice bath, 30 min), warming to room temp.; expelling excess COCl2 (N2-stream), evapn., extn. (Et2O), filtration, evapn., chromy. (SiO2, petroleum ether), distn. (bath temp. 85°C, 0.001 torr); elem. anal.;
参考文献
Knox; Pauson; Willison; Solcaniova; Toma
Organometallics, 1990 , vol. 9, # 2 p. 301 - 306