反应条件
[Pd(PPh3)2] in tetrahydrofuran
(N2); at 0°C, Fe complex dissolved in THF, ZnCl2 added in a portion, stirred for 1 h at this temp., a soln. of Pd(PPh3)2 added, stirred for 5 min, a soln. of IC6H3(CH2NMe2)2-3,5 added, allowed to warm to 25°C, stirred for 2 d; quenched with a soln. of NaOH, the aq. phase sepd., extd. with CHCl3, the combined org. phases dried (MgSO4), filtered, evapd. (vac.), chromd. (alumina, Et2O, Et2O/THF, MeOH), obtained as an oil; elem. anal.;
参考文献
Koecher, Stefan; van Klink, Gerard P.M.; van Koten, Gerard; Lang, Heinrich
Journal of Organometallic Chemistry, 2003 , vol. 684, # 1-2 p. 230 - 234
