in acetonitrile
(Cp2(CO)3Fe2(CHCH2))PF6 stirred in MeCN at 35° for 2 h; concd. in vac., extd. with hexane, passed through Al2O3 plug, rotary-evapd. at ambient temp., hexane-insol. fraction dried in high vac. for 2 h, recrystd. by dissolution in MeCN, filtration, and pptn. with Et2O;
参考文献
Casey, Charles P.; Marder, Seth R.; Colborn, Robert E.; Goodson, Patricia A.
Organometallics, 1986 , vol. 5, p. 199 - 203
in dichloromethane
V- and Fe-complexes were dissolved in CH2Cl2 with stirring for 15 min, CNtBu was added, stirred for 5 min under N2; volatiles were removed in vacuo, washed with pentane, dried in vacuo, redissolved in CH2Cl2, filtered, pentane was added with stirring, filtered, dried in vacuo; elem. anal.;
参考文献
Brunker, Tim J.; Cowley, Andrew R.; O'Hare, Dermot
Organometallics, 2002 , vol. 21, # 15 p. 3123 - 3138
Donovan-Merkert, Bernadette T.; Clontz, C. Reid; Rhinehart, Leslie M.; Tjiong, Howard I.; Carlin, Clifford M.; Cundari, Thomas R.; Rheingold, Arnold L.; Guzei, Ilia
Organometallics, 1998 , vol. 17, # 9 p. 1716 - 1724
in not given
byproducts: (CH3C6H4S)2; ratio Au/Fe equal 1/1;
参考文献
Chen, Jinhua; Jiang, Tong; Wei, Gang; Mohamed, Ahmed A.; Homrighausen, Craig; Krause Bauer, Jeanette A.; Bruce, Alice E.; Bruce, Mitchell R. M.
Journal of the American Chemical Society, 1999 , vol. 121, # 39 p. 9225 - 9226
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride in tetrahydrofuran
a mixt. in THF was stirred for 72 h at room temp. (Ar); poured into 10percent aq. HCl, extd. with CH2Cl2, washed with water, dried over MgSO4, solvent was removed in vac., flash chromy. on silica gel (isohexane, isohexane-CH2Cl2); crystd. from hexane;
参考文献
Kasak; Miklas; Putala
Journal of Organometallic Chemistry, 2001 , vol. 637-639, p. 318 - 326
