反应条件
in dichloromethane
byproducts: CH3CCCH3; under dry N2 atm.; to stirred soln. of alkyne and Fe(C5H5)2PF6 in CH2Cl2added Mo complex; after 45 min solvent removed (vac.); solid washed (Et2O); residue redissolved in CH2Cl2; filtered through Celite; toluene added; vol. reduced (vac.); ppt. was obtained; second purification using CH2Cl2-Et2O gave crystalline solid; elem. anal.;
参考文献
Adams, Christopher J.; Bartlett, Ian M.; Boonyuen, Supakorn; Connelly, Neil G.; Harding, David J.; Hayward, Owen D.; McInnes, Eric J. L.; Orpen, A. Guy; Quayle, Michael J.; Rieger, Philip H.
Dalton Transactions, 2006 , # 28 p. 3466 - 3477