in not given
diazotization under aprotic conditions;;
参考文献
Gmelin Handbook: Fe: Org.Verb.A1, 2.1.3, page 24 - 28
Full Text Show Details
Roling, P. V.
Diss. Abstr. Intern. B, Diss. Univ. of Massachusetts, Amherst, Mass., 1971, S. 1/172 1971 , vol. 31, p. 6520
Wilkinson, G.; Cotton, F. A.; Birmingham, J. M.
Journal of Inorganic and Nuclear Chemistry, 1956 , vol. 2, p. 95 - 113
Full Text Show Details
Gmelin Handbook: Fe: Org.Verb.A1, 2.1.2.3, page 23 - 24
in tetrahydrofuran
under Ar, at room temp., 24 h; addn. of toluene to a mixture of the hydrido-complex and the butyl-complex, standing of soln. (2 h, 100°C), filtration after cooling, addn. of pentane to residue, ferrocene is obtained at -30°C, distn.of residue (vac.), elem. anal.;
in tetrahydrofuran
(N2); to a suspn. of FeBr2*DME in THF at -80°C is added Li(C5Me5), mixt. is stirred for 10 min, addn. of CpNa in THF, stirred for 10 min at -80°C, warmed to room temp. during 2 h; evapn. of solvent, residue is extd. with pentane, filtered through Al2O3, evapn. of solvent;
参考文献
Koelle, U.; Fuss, B.; Khouzami, F.; Gersdorf, J.
Journal of Organometallic Chemistry, 1985 , vol. 290, p. 77 - 84
sodium bromide in dimethyl sulfoxide
Electrolysis; soln. of NaBr and ligands in DMSO electrolysis on iron anode, then reaction mixture pouring to water; ppt. and supernatant extracting (hexane), ferrocene obtaining from hexane extracts, aq. layer extracting with benzene, benzene extract evapn. yielding heteroligand complex, CsCl addn. to aq. phase yielding Cs-salt ofdicarbollide complex;
参考文献
Shirokii; Knizhnikov; Vinokurov; Bazhanov; Mayer
Russian Journal of General Chemistry, 1997 , vol. 67, # 8 p. 1185 - 1187
