in tetrahydrofuran
byproducts: lithium chloride; under inert atm. FcLi generated by react. FcSnBu3 with n-BuLi in THF at -78°C, after 90 min react. mixt. was warmed to -40°C CH2CHSiCl3 in THF was added dropwise, warmed to room temp. and stirred overnight; soln. was concd., treated with hexane, filtered, solvent was removed, residue was chromd. on silica; elem. anal.;
参考文献
Bruna, Sonia; Gonzalez-Vadillo, Ana M; Nieto, Daniel; Pastor, Cesar; Cuadrado, Isabel
Organometallics, 2010 , vol. 29, # 12 p. 2796 - 2807
in cyclohexane
byproducts: LiPF6; (N2 or Ar); heated at 80°C for 24 h; quenched with wet n-hexane, passed through silica gel, washed (ether), the org. portions combined, evapd. (vac.), flash-chromd. (silica gel, n-hexane);
in diethyl ether
under exclusion of air; preparation of small amts.;;
参考文献
Gmelin Handbook: Fe: Org.Verb.A1, 2.1.2.3, page 23 - 24
Full Text Show Details
Studiengesellschaft Kohle m. b. H.
Patent: FR1343770 , 1963 ;
C. A., 1964 , vol. 60, p. 8062/3
in neat (no solvent)
heating FeC2O4*2H2O in stream of N2 at 200°C, treatment with mixt. of C5H6 and CO at 380°C;;
参考文献
Gmelin Handbook: Fe: Org.Verb.A1, 2.1.1.1, page 15 - 16
Full Text Show Details
Holzapfel, H.; Huebner, H.; Geissler, C.; Rolle, W.
Patent: DE43979 , 1965 ;
C. A., 1966 , vol. 64, p. 17642
Gmelin Handbook: Fe: Org.Verb.A1, 2.1.2.3, page 23 - 24
Full Text Show Details
Reynolds, L. T.; Wilkinson, G.
Journal of Inorganic and Nuclear Chemistry, 1956 , vol. 2, p. 246 - 253
Sato, M.; Motoyama, I.; Hata, K.
Bulletin of the Chemical Society of Japan, 1970 , vol. 43, p. 2213 - 2217
Full Text Show Details
Gmelin Handbook: Fe: Org.Verb.A1, 5.1.2.1.5, page 372 - 380
Sato, M.; Motoyama, I.; Hata, K.
Bulletin of the Chemical Society of Japan, 1970 , vol. 43, p. 2213 - 2217
Full Text Show Details
Gmelin Handbook: Fe: Org.Verb.A1, 5.1.2.1.5, page 372 - 380
in xylene
all reactions under dry Ar,mixt. heated for 1,5 h at 120°C; products extd. (benzene), soln. filtered (Al2O3), benzene driven off, product chromd. (Al2O3, petroleum ether);
参考文献
Moiseev, S. K.; Meleshonkova, N. N.; Sazonova, V. A.
Sov. J. Coord. Chem. (Engl. Transl.), 1988 , vol. 14, p. 180 - 183
Koordinatsionnaya Khimiya, 1988 , vol. 14, p. 328 - 331
