Davidson, John L.; Green, Michael; Stone, F. Gordon A.; Welch, Alan J.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1976 , p. 2044 - 2053
in hexane; toluene
1 equiv. of Me2AlCl in 1.0 M hexane soln. was added to toluene soln. of Fe-compd. at -78 °C, stirring at this temp. for 1 h and at room temp. for 20 h; soln. was centrifuged, volatiles were removed in vac., THF-complex:bis-ferrocenyl-compd. ratio was 15:1 (from (1)H and (13)C NMR at 243 K);
参考文献
Wrackmeyer, Bernd; Klimkina, Elena V.; Ackermann, Tamara; Milius, Wolfgang
Inorganic Chemistry Communications, 2007 , vol. 10, # 7 p. 743 - 747
in hexane; dichloromethane-d2
(exclusion of air and moisture), suspn. of Al-Fe complex in CD2Cl2 cooled to -50°C treated with 2 equiv. of Me3Al in hexanes, stirred for30 min at room temp.; evapd.(vac.), dissolved (toluene-d8), centrifuged;
参考文献
Wrackmeyer, Bernd; Klimkina, Elena V.; Milius, Wolfgang
European Journal of Inorganic Chemistry, 2009 , # 21 p. 3163 - 3171
in hexane; cyclohexane
byproducts: LiPF6; (N2 or Ar); C4H9Li in hexane added at room temp. to a cyclohexane soln. of B compd., stirred for 6 h at room temp., Fe complex added, heated at 80°C for 24 h; quenched with wet n-hexane, passed through silica gel, washed (ether), the org. portions combined, evapd. (vac.), flash-chromd. (silica gel, n-hexane);
in tetrahydrofuran
byproducts: pyrazole; (under Ar, Schlenk); mixt. of Fe-complex and Na-salt in THF stirred for 45 min at room temp.; solvent evapd. in vacuo, residue extd. with THF, Al2O3 column chromy. with hexane, THF, washed with EtOH, H2O, acetone, dried in vacuo; elem. anal.;
参考文献
Babin; Belousov; Belousova; Borisov; Gumenyuk; Nekrasov
Russian Chemical Bulletin, 2011 , vol. 60, # 10 p. 2081 - 2087
in acetonitrile-D3
T=-50 - 20°C; 12 h; GloveboxSchlenk techniqueInert atmosphere;
参考文献
Zheng, Bo; Tang, Fengzhi; Luo, Jia; Schultz, Jason W.; Rath, Nigam P.; Mirica, Liviu M.
Journal of the American Chemical Society, 2014 , vol. 136, # 17 p. 6499 - 6504
in not given
addn. of C5H6 to Fe(2+) halogenide at ambient temp. and presence of high excess of NaOCH3;;
参考文献
Cordes, H.
Angewandte Chemie, 1965 , vol. 77, p. 1017 - 1017
Full Text Show Details
Cordes, H.
Zeitschrift fuer Naturforschung, 1966 , vol. 21 b, p. 746 - 751
Full Text Show Details
Gmelin Handbook: Fe: Org.Verb.A1, 2.1.1.2, page 16 - 18
in not given
addn. of C5H6 to Fe(2+) halogenide at ambient temp. and presence of high excess of NaOC2H5;;
参考文献
Cordes, H.
Angewandte Chemie, 1965 , vol. 77, p. 1017 - 1017
Full Text Show Details
Cordes, H.
Zeitschrift fuer Naturforschung, 1966 , vol. 21 b, p. 746 - 751
Full Text Show Details
Gmelin Handbook: Fe: Org.Verb.A1, 2.1.1.2, page 16 - 18
