Bitterwolf, T. E.; Ling, A. C.
Syn. Reactiv. Inorg. Metal-Org. Chem., 1977 , vol. 7, p. 367 - 372
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Bitterwolf, T. E.
Diss. Abstr. Intern. B, Diss. West Virginia Univ. 1977, S. 1/183 1977 , vol. 38, p. 1073
in tetrahydrofuran
(N2); addn. of lithium salt to a soln. of sodium salt in THF, diln. withTHF, cooling to 0°C, addn. of iron complex, stirring for 24 h at 25°C; evapn., extn. with hexanes, column chromy (Al2O3, hexanes);
参考文献
Hilbig, Harald; Koehler, Frank H.; Moertl, Klaus
Journal of Organometallic Chemistry, 2001 , vol. 627, # 1 p. 71 - 79
in dichloromethane
a soln. of the Perrier complex (from CH3COCl and AlCl3) in CH2Cl2 is added to a stirred soln. of methoxyferrocene in CH2Cl2 at 0°C; the mixt. is poured onto an ice-water slush containing a few drops of TiCl3, the organic phase is separated, the aq. phase is extd. with CH2Cl2, dried and evaporated under reduced pressure, purifn. by chromy. on a preparative TLC plate;
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McCabe, Richard W.; Parry, David E.; Saberi, Stephen P.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1993 , # 9 p. 1023 - 1030
in dichloromethane-d2
(under N2, Schlenk); soln. of Pt-complex in CD2Cl2 loaded in NMR tube, soln. of Fe-complex in CD2Cl2 added, kept in dark, MeCN added; monitored by NMR;
参考文献
Wik, Bror J.; Tilset, Mats
Journal of Organometallic Chemistry, 2007 , vol. 692, # 15 p. 3223 - 3230
in toluene
(N2, Schlenk) propargyl alcohol was added to a soln. of complex in toluene, the mixt. was stirred at reflux overnight, cooled to room temp.; filtered, solvent was removed, chromy. on an alumina column with petroleum ether (ferrocene), petroleum ether - diethyl ether (1/1) - 60percent mixt. of isomers (7/1); elem. anal.;
in toluene
(N2, Schlenk) propargyl alcohol was added to a soln. of complex in toluene, the mixt. was stirred at reflux overnight, cooled to room temp.; filtered, solvent was removed, chromy. on an alumina column with petroleum ether (ferrocene), petroleum ether - diethyl ether (1/1) - 62percent mixt. of isomers (10/1); elem. anal.;
in toluene
(N2, Schlenk) propargyl alcohol was added to a soln. of complex in toluene, the mixt. was stirred at reflux overnight, cooled to room temp.; filtered, solvent was removed, chromy. on an alumina column with petroleum ether (ferrocene), petroleum ether - diethyl ether (1/1) - 55percent mixt. of isomers (6/1); elem. anal.;
