3,5-二叔丁基邻苯二酚合成路线 （共 187 条）
反应条件
sodium amalgam in toluene under N2 atm. to soln. catechol in toluene at 0°C BBr3 was added dropwise, stirred at 0°C for 0.5 h and allowed to warm to room temp., Na/Hg amalgam was added and heated at 90°C under N2 for 5 h; soln. was filtered and evapd., residue was recrystd. from toluene/pentane at -35°C;
参考文献
Anastasi, Natia R.; Waltz, Karen M.; Weerakoon, Wimali L.; Hartwig, John F.
Organometallics, 2003 , vol. 22, # 2 p. 365 - 369
反应条件
in diethyl ether N2-atmosphere; addn. of 2 equiv. substituted catechol to B-compd. at 0°C; dropwise addn. of excess 1 M HCl in Et2O, stirring at 0°C overnight, extn. into PhMe, filtration (Celite), concn., crystn. (-30°C,24 h), collection, washing (hexanes), drying (vac.); elem. anal.;
参考文献
Lawlor, Fiona J.; Norman, Nicholas C.; Pickett, Nigel L.; Robins, Edward G.; Nguyen, Paul; Lesley, Gerry; Marder, Todd B.; Ashmore, Jennifer A.; Green, Jennifer C.
Inorganic Chemistry, 1998 , vol. 37, # 20 p. 5282 - 5288
反应条件
in benzene byproducts: CH3OH; (high vacuum system), 12h at 20°C; benzene replaced by pentane, pptd., filtered off, elem. anal.;
参考文献
Journal of Organometallic Chemistry, , vol. 315, p. 157 - 164
反应条件
in pyridine under N2, LiBH4 was dissolved in pyridine, the phenol compd. was added, 10 h, reflux for 20 h; monitored by (11)B NMR; some other minor signals were also detected;
参考文献
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, , vol. 61, # 9 p. 1079 - 1093
反应条件
sulfuric acid in benzene 1 h;
参考文献
Russian Journal of Organic Chemistry, , vol. 47, # 9 p. 1310 - 1312
反应条件
in tetrahydrofuran; ethanol byproducts: H2O2;
参考文献
Bianchini, Claudio; Mealli, Carlo; Meli, Andrea; Proserpio, Davide M.; Peruzzini, Maurizio; et al.
Journal of Organometallic Chemistry, 1989 , vol. 369, p. C6 - C11
反应条件
in nitromethane byproducts: H2O2; 90°C;
参考文献
Barbaro, Pierluigi; Bianchini, Claudio; Mealli, Carlo; Meli, Andrea
Journal of the American Chemical Society, 1991 , vol. 113, # 8 p. 3181 - 3183
反应条件
[CoII(3,5-ditert-butylsemiquinonate)(hydrotris(3,5-dimethylpyrazolyl)borate)]; oxygen in toluene T=39.84°C; P=760.051 Torr; pH=4.4; 24 h; Inert atmosphere;
参考文献
Ikeda, Atsushi; Hoshino, Kazuya; Komatsuzaki, Hidehito; Satoh, Minoru; Nakazawa, Jun; Hikichi, Shiro
New Journal of Chemistry, 2013 , vol. 37, # 8 p. 2377 - 2383
反应条件
[Cu2(4,5-bis(phenylalanyl-N-methyl)-2-methylimidazole)(H2O)2]NO3*4H2O in methanol T=25°C; pH=7 - 9.5; Catalytic behavior;
参考文献
Monte-Perez, Ines; Sosa, Ana M.; Bernes, Sylvain; Aliaga-Alcalde, Nuria; Ugalde-Saldivar, Victor M.; Gasque, Laura
European Journal of Inorganic Chemistry, 2012 , # 29 p. 4739 - 4749
反应条件
oxygen; pyridine; bipyridine; iron(III) chloride in 1,4-dioxane
T=25°C; P=760 Torr; 24 h; Further byproducts given;
参考文献
Funabiki,T.; Mizoguchi,A.; Sugimoto,T.
Journal of the American Chemical Society, 1986 , vol. 108, p. 2921
