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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
102632-99-5
合成路线
(共 8 条)
102632-99-5
→
反应条件
1011-61-6
反应条件
dihydrogen peroxide; sodium hydrogencarbonate; (HSiMe2)2NH; dihydrogen hexachloroplatinate Multistep reaction;
参考文献
Tamao, Kohei; Tanaka, Tetsu; Nakajima, Takashi; Sumiya, Ritsuo; Arai, Hitoshi; Ito, Yoshihiko
Tetrahedron Letters, 1986 , vol. 27, # 29 p. 3377 - 3380
102632-99-5
+
100-52-7
苯甲醛
→
反应条件
反应条件
[RhCl(η2:η2-cycloocta-1,5-diene)]2; potassium tert-butylate; triphenylphosphine in tetrahydrofuran T=40°C; 18 h; optical yield given as percent de;
参考文献
Advanced Synthesis and Catalysis, , vol. 351, # 16 p. 2657 - 2666
102632-99-5
→
反应条件
3240-29-7
1-苯基-4-戊烯-1-酮
反应条件
dipyridinium dichromate in dichloromethane T=20°C; 12 h;
参考文献
Zhu, Jia-Liang; Chan, Yu-Hui
Synlett, 2008 , # 8 p. 1250 - 1254
1427728-80-0
+
102632-99-5
→
反应条件
3240-29-7
1-苯基-4-戊烯-1-酮
+
58193-48-9
反应条件
tris-(dibenzylideneacetone)dipalladium(0); bis[2-(diphenylphosphino)phenyl] ether; sodium t-butanolate in toluene T=80°C; 3 h; Inert atmosphere;
参考文献
Nicolai, Stefano; Sedigh-Zadeh, Raha; Waser, Jeroime
Journal of Organic Chemistry, 2013 , vol. 78, # 8 p. 3783 - 3801
102632-99-5
→
反应条件
56139-59-4
反应条件
bis[3-trifluoroacetylcampherato(1-)]cobalt(II) complex; oxygen in isopropyl alcohol T=60°C; diastereoselective reaction;
参考文献
Menendez Perez, Barbara; Schuch, Dominik; Hartung, Jens
Organic and Biomolecular Chemistry, 2008 , vol. 6, # 19 p. 3532 - 3541
102632-99-5
→
反应条件
56139-59-4
反应条件
oxygen; [Co(O2CCH3)2]*4H2O; d-Htfc in isopropyl alcohol T=60°C; diastereoselective reaction;
参考文献
Menendez Perez, Barbara; Schuch, Dominik; Hartung, Jens
Organic and Biomolecular Chemistry, 2008 , vol. 6, # 19 p. 3532 - 3541
1427728-80-0
+
102632-99-5
→
反应条件
3240-29-7
1-苯基-4-戊烯-1-酮
+
58193-48-9
反应条件
tris-(dibenzylideneacetone)dipalladium(0); bis[2-(diphenylphosphino)phenyl] ether; sodium t-butanolate in toluene T=80°C; 3 h; Inert atmosphere;
参考文献
Nicolai, Stefano; Sedigh-Zadeh, Raha; Waser, Jeroime
Journal of Organic Chemistry, 2013 , vol. 78, # 8 p. 3783 - 3801
108-86-1
溴代苯
+
102632-99-5
→
反应条件
39686-51-6
1,5-二苯基-1-戊酮
反应条件
palladium diacetate; sodium hydrogencarbonate; lithium chloride in N,N-dimethyl-formamide T=50°C; 0.5 h; Inert atmosphere; regioselective reaction;
参考文献
Crawley, Matthew L.; Phipps, Kristin M.; Goljer, Lgor; Mehlmann, John F.; Lundquist, Joseph T.; Ullrich, John W.; Yang, Cuijian; Mahaney, Paige E.
Organic Letters, 2009 , vol. 11, # 5 p. 1183 - 1185