phosphorus tribromide in DMF (N,N-dimethyl-formamide); dichloromethane T=0°C; 3 h;

1: 1-(1-bromoethyl)-3,5-diacetoxybenzene With lithium carbonate in isobutyramide T=120°C; 2 h; Inert atmosphere; 2: 1-bromo-4-acetoxybenzene With potassium phosphate; palladium oximate in isobutyramide T=130°C; 19.75 h; Inert atmosphere; 3: With water; potassium carbonate T=110°C; 2.5 h; Product distribution / selectivity;

1: 1-(1-bromoethyl)-3,5-diacetoxybenzene With lithium carbonate in N,N-dimethyl acetamide T=120°C; 2 h; Inert atmosphere; 2: 1-bromo-4-acetoxybenzene With potassium carbonate; palladium oximate (CAS 32679-19-9) in N,N-dimethyl acetamide T=130°C; Heck Reaction; 3.25 h; Inert atmosphere; 3: With water T=115°C; 2 h; Product distribution / selectivity;

1: 1-(1-bromoethyl)-3,5-diacetoxybenzene With lithium carbonate in N,N-dimethyl acetamide T=120°C; 2 h; Inert atmosphere; 2: 1-bromo-4-acetoxybenzene With potassium carbonate; palladium oximate (CAS 32679-19-9) in N,N-dimethyl acetamide T=130°C; Heck Reaction; 3.25 h; Inert atmosphere; 3: With water T=115°C; 2 h; Product distribution / selectivity;