in benzene 7.5 h; Heating;

methyl iodide

暂无反应条件数据

isopentyl nitrite in benzene 1 h; Heating;

Stage #1: <a href="#" onclick="return RXDsubstances(event, this, '606215', constants.ctx, '0')">1-phenyl-propan-1-one</a> <b>With</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '3924762', constants.ctx, '0')">potassium hydride</a>&nbsp;<b>in</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '102391', constants.ctx, '0')">tetrahydrofuran</a> <br />Metallation;&nbsp;0.25&nbsp;h;&nbsp;<br />Stage #2: <a href="#" onclick="return RXDsubstances(event, this, '1098293', constants.ctx, '0')">carbon disulfide</a> <b>With</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '1698358', constants.ctx, '0')">bis(trimethylsilyl)-sulfide</a>&nbsp;<b>in</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '102391', constants.ctx, '0')">tetrahydrofuran</a> <br />Substitution;&nbsp;0.5&nbsp;h;&nbsp;<br />Stage #3: <b>With</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '1740341', constants.ctx, '0')">1,2,2-trichloro-1,1,2-trichloro-ethane</a>&nbsp;<b>in</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '102391', constants.ctx, '0')">tetrahydrofuran</a> <br />T=0&deg;C;&nbsp;Oxidation;&nbsp;0.333333&nbsp;h;&nbsp;<br /> &nbsp;

<b>Multi-step reaction with 2 steps<br /> </b>1: 1.05 M potassium tert-butoxide / dimethylformamide; benzene / 1 h / Ambient temperature<br />2: 1.) N-chlorosuccinimide; 2.) (Me₃Si)2S, imidazole / 1.) CH₂Cl₂, 0 deg C, 20 min; 2.) CH₂Cl₂, RT, 18 h<br /> <br /> &nbsp;

<b>Multi-step reaction with 2 steps<br /> </b>1: 1.) t-BuOK, 2.) methanesulfonic acid / 1.) THF, 2 h, 2.) ice bath<br />2: 71 percent / liquid hydrogensulfide, bromine / CH₂Cl₂ / 6 h / ice-acetone bath, other 3-oxo dithioic acids<br /> <br /> &nbsp;