Su, Weiping; Urgaonkar, Sameer; McLaughlin, Patrick A.; Verkade, John G.
Journal of the American Chemical Society, 2004 , vol. 126, # 50 p. 16433 - 16439
potassium fluoride; tris(dibenzylideneacetone)dipalladium (0); tri-cyclo-hexyl-phosphine in tetrahydrofuran
T=60°C; Suzuki cross-coupling; 48 h; Title compound not separated from byproducts.;
参考文献
Littke, Adam F.; Dai, Chaoyang; Fu, Gregory C.
Journal of the American Chemical Society, 2000 , vol. 122, # 17 p. 4020 - 4028
1: 2,6-dimethylphenyl MgBr With zinc(II) chloride in tetrahydrofuran
T=20°C; 0.333333 h;
2: ortho-chlorotoluene With Pd0(tris(tert-butyl)phosphine)2 in tetrahydrofuran; 1-methyl-pyrrolidin-2-one
T=100°C; Negishi reaction; 18 h; Further stages.;
参考文献
Dai; Fu
Journal of the American Chemical Society, 2001 , vol. 123, # 12 p. 2719 - 2724
1: 2-methylphenylmagnesium chloride With zinc(II) chloride in tetrahydrofuran
T=20°C; 0.333333 h;
2: 2-Chloro-1,3-dimethylbenzene With Pd0(tris(tert-butyl)phosphine)2 in tetrahydrofuran; 1-methyl-pyrrolidin-2-one
T=100°C; Negishi reaction; 24 h; Further stages.;
参考文献
Dai; Fu
Journal of the American Chemical Society, 2001 , vol. 123, # 12 p. 2719 - 2724
