2-甲基-2,3-二苯基环氧乙烷合成路线 （共 11 条）
反应条件
oxone; 1-(2-trifluoromethyl)pyrrollidinium triflate; sodium hydrogencarbonate in acetonitrile
参考文献
Armstrong, Alan; Ahmed, Ghafoor; Garnett, Ian; Goacolou, Katell; Wailes, J. Steven
Tetrahedron, 1999 , vol. 55, # 8 p. 2341 - 2352
反应条件
tetramethylene sulfide; dirhodium tetraacetate; N-benzyl-N,N,N-triethylammonium chloride in acetonitrile T=40°C; 3 h;
参考文献
Aggarwal, Varinder K.; Alonso, Emma; Hynd, George; Lydon, Kevin M.; Palmer, Matthew J.; Porcelloni, Marina; Studley, John R.
Angewandte Chemie - International Edition, 2001 , vol. 40, # 8 p. 1430 - 1433
反应条件
sodium chlorite; (ethylenedinitrilo)tetraacetic acid disodium salt in water; acetonitrile T=55 - 65°C; 21 h;
参考文献
Geng, Xue-Li; Wang, Zhi; Li, Xiao-Qiang; Zhang, Chi
Journal of Organic Chemistry, 2005 , vol. 70, # 23 p. 9610 - 9613
反应条件
copper acetylacetonate; dimethylsulfide in dichloromethane T=25 - 35°C; 3 h;
参考文献
Aggarwal, Varinder K.; Abdel-Rahman, Hesham; Fan, Li; Jones, Ray V. H.; Standen, Mike C. H.
Chemistry--A European Journal, 1996 , vol. 2, # 8 p. 1024 - 1030
反应条件
1: trans-2,3-diphenyloxirane With n-butyllithium in tetrahydrofuran; hexane T=-60°C; 2 h; 2: methyl iodide in tetrahydrofuran; hexane T=-60 - 20°C;
参考文献
Florio, Saverio; Aggarwal, Varinder; Salomone, Antonio
Organic Letters, 2004 , vol. 6, # 23 p. 4191 - 4194
反应条件
1.1: 73 percent / tetrahydrofuran / 1 h / 20 °C 2.1: NaHMDS / tetrahydrofuran / 1 h / -78 °C 2.2: 74 percent / tetrahydrothiophene; rhodium(II) acetate dimer; benzyl triethylammonium chloride / 12 h / 30 °C View Scheme
参考文献
Aggarwal, Varinder K.; Alonso, Emma; Hynd, George; Lydon, Kevin M.; Palmer, Matthew J.; Porcelloni, Marina; Studley, John R.
Angewandte Chemie - International Edition, 2001 , vol. 40, # 8 p. 1430 - 1433
反应条件
1: trans-2,3-diphenyloxirane With N,N,N',N,-tetramethylethylenediamine; sec.-butyllithium in tetrahydrofuran; cyclohexane T=-98°C; 1 h; 2: methyl iodide in tetrahydrofuran; cyclohexane T=-98 - 20°C;
参考文献
Florio, Saverio; Aggarwal, Varinder; Salomone, Antonio
Organic Letters, 2004 , vol. 6, # 23 p. 4191 - 4194
反应条件
1.1: n-BuLi / tetrahydrofuran; hexane / 1.5 h / -78 °C 1.2: tetrahydrofuran; hexane 2.1: n-BuLi / tetrahydrofuran; hexane / 2 h / -60 °C 2.2: tetrahydrofuran; hexane / -60 - 20 °C View Scheme
参考文献
Florio, Saverio; Aggarwal, Varinder; Salomone, Antonio
Organic Letters, 2004 , vol. 6, # 23 p. 4191 - 4194
反应条件
pyridine; tetrabutylammomium bromide; copper(I) bromide in N,N-dimethyl-formamide T=-10 - -5°C; Electrochemical reaction; Title compound not separated from byproducts;
参考文献
Oudeyer; Leonel; Paugam; Nedelec
Synthesis, 2004 , # 3 p. 389 - 400
反应条件
(R,R)-(salen)Cr(III)-Cl in dichloromethane T=20°C; 36 h;
参考文献
Bartoli, Giuseppe; Bosco, Marcella; Carlone, Armando; Locatelli, Manuela; Massaccesi, Massimo; Melchiorre, Paolo; Sambri, Letizia
Organic Letters, 2004 , vol. 6, # 13 p. 2173 - 2176
