in neat (no solvent) byproducts: NaBr, HBr; (Ar); addn. of NaNH2 into crucible with BBr3 at room temp.; washing with water and abs. EtOH for several times; vac.-drying at 60°C for 4 h;
H2 Kinetics; byproducts: NH4Br; cold-wall reactor heated by IR lamps, ratio NH3/BBr3=3.0, NH3/H2 introducing into uppermost part, Ar satd. with BBr3 at 0°C introducing 2cm above graphite plate substrate, total gas pressure 2-12 kPa, substra te temp. 800-1200°C, 20 min; SEM;
参考文献
Choi, Byung-Jin
Materials Research Bulletin, 1999 , vol. 34, # 14 p. 2215 - 2220
in neat (no solvent) formation out of SnCl4 at slow addn. of BBr3 at or under room temperature;; pure;;
参考文献
Druce, P. M.; Lappert, M. F.; Riley, P. N. K.
Chemical Communications (London), 1967 , p. 486 - 487
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Gmelin Handbook: Sn: MVol.C1, 7.7.1.3, page 387 - 388
