反应条件
in neat (no solvent) reaction carried out in Pyrex tubes to which Teflon valves had been sealed or in a N2-filled glovebox; reaction of B2Cl4 with excess B5H9 in a 1:3 mole ratio; vessel allowed to warm from -196 ° C to ambient temp., 20 min at ambient temp.,; fractionation, yield of 1-BCl2B5H8 based upon amt. of B2Cl4 employed: 73percent, based upon amt. of B5H9 consumed: 95percent; small amts. of B2H6, BCl2H, B2H5Cl, also material insufficiently volatileto move into vac. line formed;;
参考文献
Inorganic Chemistry, , vol. 29, p. 4174 - 4179
