iron(III) chloride in dichloromethane byproducts: BCl2(OC2H5); slow addn. of boronate to BCl3 soln. contg. FeCl3 under N2, 0°C, within 10 min; stirring at 0°C, 1 h and at 25°C, 1 h; evapn.; extn. (CH2Cl2); evapn.; distn.;
参考文献
Brown, Herbert C.; Salunkhe, Ashok M.; Argade, Ankush B.
Organometallics, 1992 , vol. 11, p. 3094 - 3097
in benzene BCl3 cooled at -78°C and quickly added to Sn(C6H5)4, cooled at 5°C while stirring; warming at ambient temp., boiled for 3.5 h using back-flow; best lab. method; solvent must be distd. below 140°C (immersion thermometer!); crude product distd. between 150-200°C; fractional vac. distn.;
Burch, J. E.; Gerrard, W.; Howarth, M.; Mooney, E. F.
Journal of the Chemical Society, 1960 , p. 4916 - 4918
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Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.16.1.4.4, page 157 - 159
Koester, R.; Grassberger, M. A.
Liebigs Annalen der Chemie, 1968 , vol. 719, p. 169 - 186
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Gmelin Handbook: B: B-Verb.9, 5.2.4, page 189 - 199
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in dichloromethane-d2 byproducts: B3Cl3O3; under N2, stirred at room temp. for 1 h; decanted in an NMR tube, cooled to -196°C and sealed; NMR;
参考文献
Workman, David P.; Jan, Deng-Yang; Shore, Sheldon G.
Inorganic Chemistry, 1990 , vol. 29, p. 3518 - 3525
Brindley, P. B.; Gerrard, W.; Lappert, M. F.
Journal of the Chemical Society, 1956 , vol. 1956, p. 824 - 828
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Gmelin Handbook: B: B-Verb.9, 5.2.4, page 189 - 199
