Al or Mg or Zn or Na
leading BCl3-H2 mixt. over hot metal powder at 300-500°C;
参考文献
Hurd, D. T.
Journal of the American Chemical Society, 1949 , vol. 71, p. 20 - 22
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Gmelin Handbook: B: B-Verb.9, 2.1.2.1, page 45 - 47
silver in gas
continuous process; 700°C; molar ratio H2:BCl3 = 14:1; contact time 0.2-0.5 s; rapid cooling of react. gas to avoid symmetrysation of HBCl2 to BCl3 and B2H6;
Myers, H. W.; Putman, R. F.
Inorganic Chemistry, 1963 , vol. 2, p. 655 - 657
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Gmelin Handbook: B: B-Verb.9, 1.2.2.1, page 15 - 20
Gmelin Handbook: B: B-Verb.9, 1.2.2.1, page 15 - 20
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Witz, S.; Shepherd, J. L.; Hormats, E. I.
Patent: US3329485 , 1967 ;
C.A., 1967 , vol. 67, p. 108741
flowing equimolar amts. of BCl3 and H2 through quartz pipe heated to 900°C; residence time 1.7 s;
参考文献
Myers, H. W.; Putman, R. F.
Inorganic Chemistry, 1963 , vol. 2, p. 655 - 657
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Gmelin Handbook: B: B-Verb.9, 1.2.2.1, page 15 - 20
