magnesium
obtained HCl can be removed from react. mixt. since it reacts with metal;
参考文献
Cueilleron, J.; Reymonet, J. L.
Bulletin de la Societe Chimique de France, 1967 , p. 1367 - 1370
Full Text Show Details
Gmelin Handbook: B: B-Verb.9, 1.2.2.1, page 15 - 20
Gmelin Handbook: B: B-Verb.9, 1.2.2.1, page 15 - 20
Full Text Show Details
Witz, S.; Shepherd, J. L.; Hormats, E. I.
Patent: US3329485 , 1967 ;
C.A., 1967 , vol. 67, p. 108741
Electric Arc; H2 in 2-10-fold molar excess; 750°C react. temp. reached by preheating part of H2 to >2500°C and mixing it to rest of H2 prehaeted to <1000°C and BCl3 preheated to 500 °C; formation of boron reduced this way;
参考文献
Gmelin Handbook: B: B-Verb.9, 1.2.2.1, page 15 - 20
Full Text Show Details
Cooper, H. B. H.
Patent: US3684462 , 1972 ;
C.A., 1972 , vol. 77, p. 141952
26°C; 30 Torr; IR anal. suggests that the unstable intermediate enriched in -150 - -130°C fraction is probably unsymmetric B2H4Cl2;
参考文献
Rietti, S. B.; Lombardo J.
Journal of Inorganic and Nuclear Chemistry, 1965 , vol. 27, p. 247 - 249
Full Text View citing articles Show Details
Gmelin Handbook: B: B-Verb.9, 2.2, page 54 - 55
Gmelin Handbook: B: B-Verb.9, 1.2.2.1, page 15 - 20
Full Text Show Details
Edwards, L. J.; Pearson, R. K.
Patent: US3007768 , 1961 ;
C.A., 1962 , vol. 56, p. 11236
in neat (no solvent)
Ar-atmosphere; addn. of Me3SiH (3 equivs.) to mixt. of hexene (3 equivs.) and BCl3 under reflux (12°C), stirring at room temp. for 2 h; not sepd.; NMR spectroscopy;
参考文献
Soundararajan, Raman; Matteson, Donald S.
Organometallics, 1995 , vol. 14, p. 4157 - 4166
