React. of starting materials (vac., 150°C, 16 h).; Sepn. of volatile materials (9.5percent unreacted BCl3, Me3SiCl, MeBCl2) by fractional condensation. Identification by mass spectroscopy.;
参考文献
Paciorek, K. J. L.; Kratzer, R. H.; Nakahara, J. H.; Krone-Schmidt, W.
Inorganic Chemistry, 1989 , vol. 28, p. 2896 - 2898
React. of starting materials (vac., 150°C, 16 h).; Sepn. of volatile material (Me3SiCl, MeBCl2) by fractional condensation. Identification of resulting compounds and 5.2percent unreacted starting B-material by mass spectroscopy.;
参考文献
Paciorek, K. J. L.; Kratzer, R. H.; Nakahara, J. H.; Krone-Schmidt, W.
Inorganic Chemistry, 1989 , vol. 28, p. 2896 - 2898
in not given
formation of PH3*BCl3 by react. of PH3 with BCl3 at 25 °C; decompn. of PH3*BCl3 on heating at 300 °C;; formation of amorphous PB;;
参考文献
Vickery, R. C.
Nature (London, United Kingdom), 1959 , vol. 184, p. 268
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Besson, A.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1891 , vol. 113, p. 78 - 80
in neat (no solvent)
reaction of equimolar amounts of NHF2 and BCl3 at -130°C in vacuum; heating;; vacuum fractionation;;
参考文献
Petry, R. C.
Journal of the American Chemical Society, 1960 , vol. 82, p. 2400 - 2401
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Gmelin Handbook: Cl: SVol.B2, 130, page 588 - 590
