2-甲基-4-苯基-2-丁醇合成路线 （共 84 条）
反应条件
phosphoric acid; dihydrogen peroxide T=50°C; 6 h;
参考文献
Kropf, Heinz; Wallis, Helmut von
Synthesis, 1981 , # 3 p. 237 - 240
反应条件
[bis(acetoxy)iodo]benzene; iodine in 1,2-dichloro-ethane 2 h; Ambient temperatureIrradiation; Yields of byproduct given;
参考文献
Muraki; Togo; Yokoyama
Tetrahedron Letters, 1996 , vol. 37, # 14 p. 2441 - 2444
反应条件
1,3-Diiodo-5,5-dimethyl-2,4-imidazolidinedione in 1,2-dichloro-ethane
T=40°C; 9 h; Irradiation;
参考文献
Furuyama, Shusuke; Togo, Hideo
Synlett, 2010 , # 15 p. 2325 - 2329
反应条件
toluene-4-sulfonic acid in toluene
5 h; Heating; Yield given. Yields of byproduct given;
参考文献
Giovanelli, Emerson; Doris, Eric; Rousseau, Bernard
Tetrahedron Letters, 2006 , vol. 47, # 48 p. 8457 - 8458
反应条件
1: HBr / 3 h / 20 °C
2: K2CO3; N2H4*H2O; PhSeSePh / dimethylsulfoxide
View Scheme
参考文献
Sneeden,R.P.A.; Zeiss,H.H.
Journal of Organometallic Chemistry, 1971 , vol. 26, p. 101 - 113
反应条件
Lawesson's reagent in toluene
0.5 h; Heating; Title compound not separated from byproducts;
参考文献
Nishio, Takehiko
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1993 , # 10 p. 1113 - 1118
反应条件
1: With triethylamine tris(hydrogen fluoride); triethylamine in ethyl acetate
T=5 - 23°C; 0.0833333 h;
2: With TFFH in ethyl acetate
T=60°C; 16 h;
参考文献
Bellavance, Gabriel; Dube, Pascal; Nguyen, Bao
Synlett, 2012 , # 4 p. 569 - 572
反应条件
phosphoric acid, fully deuterated
T=230 - 240°C; 3 h; Yield given. Title compound not separated from byproducts;
参考文献
Sakhabutdinov, A. G.; Usmanova, A. G.; Frolov, P. A.; Kushnarev, D. F.; Schmidt, F. K.
Journal of Organic Chemistry USSR (English Translation), 1988 , vol. 24, # 8 p. 1452 - 1455
Zhurnal Organicheskoi Khimii, 1988 , vol. 24, # 8 p. 1610 - 1614
反应条件
phosphoric acid, fully deuterated
T=230 - 240°C; 3 h; Product distributionMechanism;
参考文献
Sakhabutdinov, A. G.; Usmanova, A. G.; Frolov, P. A.; Kushnarev, D. F.; Schmidt, F. K.
Journal of Organic Chemistry USSR (English Translation), 1988 , vol. 24, # 8 p. 1452 - 1455
Zhurnal Organicheskoi Khimii, 1988 , vol. 24, # 8 p. 1610 - 1614
反应条件
4-(N,N-dimethlyamino)pyridine; triethylamine in tetrahydrofuran
T=20°C; 2 h;
参考文献
Kuroda, Kiichi; Hayashi, Yujiro; Mukaiyama, Teruaki
Tetrahedron, 2007 , vol. 63, # 27 p. 6358 - 6364
