1: Hydrocinnamic alcohol With sodium chlorite; sodium dihydrogenphosphate; 1-MeAZADO(1+)*Cl(1-) in dichloromethane; water T=25°C; 1.5 h; 2: With 2-methyl-but-2-ene in dichloromethane; water 3: diazomethane With hydrogenchloride; sodium hydroxide Product distribution / selectivity; more than 3 stages;
参考文献
Nissan Chemical Industries, Ltd.
Patent: US2009/124806 A1, 2009 ;
Location in patent: Page/Page column 5-6 ;
hydrogen; sodium methylate; homogeneous ruthenium complex in tetrahydrofuran T=100°C; P=37503.8 Torr; 0.25 h; Title compound not separated from byproducts.;
参考文献
Angewandte Chemie - International Edition, , vol. 46, # 39 p. 7473 - 7476
