byproducts: H2, Cl2; evapn. of boron with electron bombardment at 1E-6 Torr and 2500-2800°C, condensation of boron vapor on wall of vac. chamber at -196°C, heating condensation products to -170 - (-100)°C;
参考文献
Timms, P. L.
Chemical Communications (London), 1968 , p. 258 - 259
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Gmelin Handbook: B: B-Verb.9, 1.2.2.1, page 15 - 20
Electric Arc; H2 in 2-10-fold molar excess; 750°C react. temp. reached by preheating part of H2 to >2500°C and mixing it to rest of H2 prehaeted to <1000°C and BCl3 preheated to 500 °C; formation of boron reduced this way;
参考文献
Gmelin Handbook: B: B-Verb.9, 1.2.2.1, page 15 - 20
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Cooper, H. B. H.
Patent: US3684462 , 1972 ;
C.A., 1972 , vol. 77, p. 141952
26°C; 30 Torr; IR anal. suggests that the unstable intermediate enriched in -150 - -130°C fraction is probably unsymmetric B2H4Cl2;
参考文献
Rietti, S. B.; Lombardo J.
Journal of Inorganic and Nuclear Chemistry, 1965 , vol. 27, p. 247 - 249
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Gmelin Handbook: B: B-Verb.9, 2.2, page 54 - 55
room temp.; B2H5Cl detected by IR spectroscopy after 22.5 h;
参考文献
Gmelin Handbook: B: B-Verb.9, 2.1.2.1, page 45 - 47
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Barr, J. B.
Diss. Abstr., Thesis Pennsylvania State Univ. 1961 1961 , vol. 22, p. 86/7
Gmelin Handbook: B: B-Verb.9, 1.2.2.1, page 15 - 20
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Edwards, L. J.; Pearson, R. K.
Patent: US3007768 , 1961 ;
C.A., 1962 , vol. 56, p. 11236
compn. of gas phase final product studied by IR spectroscopy;
参考文献
Gmelin Handbook: B: B-Verb.9, 2.1.2.1, page 45 - 47
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Barr, J. B.
Diss. Abstr., Thesis Pennsylvania State Univ. 1961 1961 , vol. 22, p. 86/7
100°C; starting mixt. of 52.5 percent B2H6 and 47.5 percent HCl; 740 Torr; 30 h;
参考文献
Cueilleron, J.; Reymonet, J. L.
Bulletin de la Societe Chimique de France, 1967 , p. 1370 - 1374
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Gmelin Handbook: B: B-Verb.9, 1.2.2.1, page 15 - 20
