Rh6(CO)12; tetrabutyl-ammonium chloride in benzene T=50°C; P=15200 Torr; 6 h;

[Pd(1,3-bis(diphenylphosphino)propane)(OAc)2] in toluene T=110°C; P=38000 Torr; 20 h;

1,10-phenanthroline; tri-ruthenium(0)dodecacarbonyl in N,N-dimethyl acetamide T=150°C; P=30400 Torr; 10 h;

1: β-styryl bromide With tert.-butyl lithium in diethyl ether; pentane T=-78 - 25°C; 2: With indium(III) chloride in diethyl ether; pentane T=25°C; 0.5 h; 3: iodine acetic acid diethylamide With triethyl borane; oxygen in diethyl ether; hexane; pentane T=25°C; 14 h;

[(PPh3)3Pd] in chloroform T=80°C; P=60800 Torr; 60 h; competition in Pd(0) catalyzed carbonylation; other amide;

9-borabicyclo[3.3.1]nonane dimer; dihydrogen peroxide; sodium acetate Yield given. Multistep reaction;