1: 1-bromo-4-methoxy-benzene With magnesium in tetrahydrofuran Heating; 2: (E)-1-oct-3-enyl bromide With lithium tetrachlorocuprate in tetrahydrofuran Grignard reaction;
参考文献
Vyvyan, James R.; Holst, Christian L.; Johnson, Allison J.; Schwenk, Cheryl M.
Journal of Organic Chemistry, 2002 , vol. 67, # 7 p. 2263 - 2265
1: 2-(hydroxydimethylsilyl)thiophene sodium salt With bis(η3-allyl-μ-chloropalladium(II)) in toluene 2: 1-bromo-4-methoxy-benzene With biphenyl-2-yl-di-tert-butyl-phosphane in toluene T=50°C; 3 h;
参考文献
Denmark, Scott E.; Baird, John D.
Organic Letters, 2006 , vol. 8, # 4 p. 793 - 795
1: hexaphenylcyclotrisiloxane With potassium hydroxide in 1,4-dioxane; water 1 h; Heating; 2: 1-bromo-4-methoxy-benzene With palladium diacetate in 1,4-dioxane; water 4 h; Heating; Further stages.;
cesium hydroxide; water; 1,4-di(diphenylphosphino)-butane; bis(η3-allyl-μ-chloropalladium(II)) in 1,4-dioxane; toluene T=110°C; 24 h; Title compound not separated from byproducts;
参考文献
Denmark, Scott E.; Ober, Michael H.
Advanced Synthesis and Catalysis, 2004 , vol. 346, # 13-15 p. 1703 - 1714
cesium hydroxide; water; 1,4-di(diphenylphosphino)-butane; bis(η3-allyl-μ-chloropalladium(II)) in 1,4-dioxane; toluene T=110°C; 24 h; Title compound not separated from byproducts;
参考文献
Denmark, Scott E.; Ober, Michael H.
Advanced Synthesis and Catalysis, 2004 , vol. 346, # 13-15 p. 1703 - 1714
