1: With P(t-Bu)2Me*HBF4; palladium diacetate; potassium carbonate in toluene
T=110°C; 12 h; Inert atmosphere;
2: With methanol; palladium 10 on activated carbon; ammonium formate
T=40°C; Inert atmosphere;
参考文献
Campeau, Louis-Charles; Stuart, David R.; Leclerc, Jean-Philippe; Bertrand-Laperle, Megan; Villemure, Elisia; et al.
Journal of the American Chemical Society, 2009 , vol. 131, p. 3291 - 3306
1: 1-bromo-4-methoxy-benzene With diethylaluminium chloride; diisobutylaluminium hydride; magnesium; lithium chloride in tetrahydrofuran; n-heptane
T=25°C; 3 h;
2: With CuCN*2LiCl in tetrahydrofuran
T=-10°C; Michael addition; 0.0833333 h;
3: cyclohexenon With chloro-trimethyl-silane in tetrahydrofuran
T=-10 - 25°C; Michael addition;
参考文献
Gao, Hongjun; Knochel, Paul
Synlett, 2009 , # 8 p. 1321 - 1325
