1: With [resin-CH2N(CH3)3]2CO3 in water; N,N-dimethyl-formamide
T=80°C; Suzuki coupling; 16 h;
2: With [resin-CH2N(CH3)3]2CO3; 4-{[(9-anthrylmethyl)amino]carbonyl}phenylboronic acid in water; N,N-dimethyl-formamide
T=80°C;
3: With maleimido-CH2-PS resin in water; N,N-dimethyl-formamide
T=90°C; 10 h;
参考文献
Lan, Ping; Berta, Daniela; Porco Jr., John A.; South, Michael S.; Parlow, John J.
Journal of Organic Chemistry, 2003 , vol. 68, # 25 p. 9678 - 9686
in tetrahydrofuran; benzene
(N2); SnCl4 was added to cooled and stirred Grignard soln., prepd. from p-bromoanisole and Mg in THF, and refluxed for 1 h; filtered soln. was evapd. in vac. and pptd. with acetone, crude product was dissolved in benzene and pptd. with EtOH; recrystn. from EtOH; elem. anal.;
参考文献
Wharf, Ivor; Simard, Michael G.
Journal of Organometallic Chemistry, 1987 , vol. 332, p. 85 - 94
1: 1-bromo-4-methoxy-benzene With magnesium in diethyl ether
2: carbon disulfide in diethyl ether
3: chloroacetic acid in diethyl ether
Further stages.;
参考文献
Bursavich, Matthew G.; Gilbert, Adam M.; Lombardi, Sabrina; Georgiadis, Katy E.; Reifenberg, Erica; Flannery, Carl R.; Morris, Elisabeth A.
Bioorganic and Medicinal Chemistry Letters, 2007 , vol. 17, # 20 p. 5630 - 5633
