6-甲基-6-庚烯-2-酮合成路线 （共 52 条）
反应条件
diethyl ether
Behandeln des Reaktionsprodukts mit Schwefelsaeure enthaltendem Aethanol;
参考文献
Kappeler et al.
Helvetica Chimica Acta, 1954 , vol. 37, p. 957,962
反应条件
lithium aluminium tetrahydride; aluminium trichloride; sodium hydride
1.) ether, 25 deg C, 1 h, 2.) 10 h, 3.) 0 deg C, 1 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Dhokte, U. P.; Rao, A. S.
Synthetic Communications, 1988 , vol. 18, # 8 p. 811 - 822
反应条件
sodium hydride
1.) ether, 25 deg C, 1 h, 2.) 10 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Dhokte, U. P.; Rao, A. S.
Synthetic Communications, 1988 , vol. 18, # 8 p. 811 - 822
反应条件
1.1: sodium hydride / tetrahydrofuran
1.2: 71.3 percent / tetrahydrofuran
2.1: 74.2 percent / LiAlH4 / diethyl ether / 12 h / cooling
View Scheme
参考文献
Kappeler et al.
Helvetica Chimica Acta, 1954 , vol. 37, p. 957,962
反应条件
lithium aluminium tetrahydride; aluminium trichloride; sodium hydride
1.) ether, 25 deg C, 1 h, 2.) 10 h, 3.) 0 deg C, 1 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Dhokte, U. P.; Rao, A. S.
Synthetic Communications, 1988 , vol. 18, # 8 p. 811 - 822
反应条件
sodium hydride
1) ether, reflux, 2) reflux, 7 h; Yield given. Multistep reaction;
参考文献
LaLonde, R. T.; Muhammad, N.; Wong, C. F.; Sturiale, E. R.
Journal of Organic Chemistry, 1980 , vol. 45, p. 3664 - 3671
反应条件
boron trifluoride diethyl etherate; toluene-4-sulfonic acid hydrazide
参考文献
Wilson, R. Marshall; Rekers, John W.; Packard, Alan B.; Elder, R. C.
Journal of the American Chemical Society, 1980 , vol. 102, # 5 p. 1633 - 1641
反应条件
3-chloro-benzenecarboperoxoic acid
参考文献
Wilson, R. Marshall; Rekers, John W.
Journal of the American Chemical Society, 1981 , vol. 103, # 1 p. 206 - 207
反应条件
1: diethyl ether / Behandeln des Reaktionsprodukts mit Schwefelsaeure enthaltendem Aethanol
2: H2SO4; formic acid
View Scheme
参考文献
Kappeler et al.
Helvetica Chimica Acta, 1954 , vol. 37, p. 957,962
反应条件
Yield given. Multistep reaction;
参考文献
Julia, M.; Schmitz, C.
Bulletin de la Societe Chimique de France, 1986 , # 4 p. 630 - 636
