氢化物三(三甲基甲硅烷基)锗合成路线 （共 12 条）
反应条件
H2SO4 in tetrahydrofuran; diethyl ether; water (Ar); soln. of Ge compd. in THF was added to aq. H2SO4/ether; layers septd.; ether phase dried (Na2SO4); concd. (vac.);
参考文献
Fischer, Jelena; Baumgartner, Judith; Marschner, Christoph
Organometallics, 2005 , vol. 24, # 6 p. 1263 - 1268
反应条件
in diethyl ether under Ar; Et2O soln. of Ge deriv., excess of concd. HCl and nonadecan (internal standard) stirred at room temp. for 2 h;
参考文献
Nanjo, Masato; Oda, Takashi; Mochida, Kunio
Journal of Organometallic Chemistry, 2003 , vol. 672, # 1-2 p. 100 - 108
反应条件
1: toluene 2: H2SO4 / water; tetrahydrofuran; diethyl ether View Scheme
参考文献
Organometallics, , vol. 24, # 6 p. 1263 - 1268
反应条件
in hexane Ar-atmosphere; stirring at -78°C for 9 h, warming to room temp., stirring for 15 h; solvent removal (vac.), stirring with pentane for 1 h, filtration, evapn., repeated recrystn.;
参考文献
Inorganic Chemistry, , vol. 36, # 27 p. 6247 - 6250
反应条件
HCl in diethyl ether Ar-atmosphere; room temp., 5 days; addn. of 10percent HCl, extn. (ether); product mixt. not sepd., detd. by (1)H-NMR spectroscopy;
参考文献
Inorganic Chemistry, , vol. 33, p. 1115 - 1120
反应条件
1: tetrakis(trimethylsilyl)germanium With potassium tert-butylate 2: hydrogenchloride in water
参考文献
Journal of Organometallic Chemistry, , vol. 727, p. 50 - 59
反应条件
1: diethyl ether View Scheme
参考文献
Chemistry Letters, , # 1 p. 108 - 109
反应条件
in hexane Ar-atmosphere; stirring stoich. amts. at -78°C for 9 h, warming to room temp., stirring for 15 h; solvent removal (vac.), stirring with pentane for 1 h, filtration, concn. of filtrate, crystn. (-78°C, 6 h); further crop on concn. of filtrate; elem. anal.;
参考文献
Inorganic Chemistry, , vol. 36, # 27 p. 6247 - 6250
反应条件
in hexane Ar-atmosphere; dropwise addn. of GeCl4 to 2 equiv. of Li-compd. (-78°C, stirring (-78°C, 12 h), slow warming to ambient temp., stirring (36 h); product mixt. not sepd., detd. by (1)H-NMR spectroscopy;
参考文献
Inorganic Chemistry, , vol. 33, p. 1115 - 1120
反应条件
in hexane Ar-atmosphere; stirring stoich. amts. at -78°C for 9 h, warming to room temp., stirring for 15 h; solvent removal (vac.), stirring with pentane for 1 h, filtration, concn. of filtrate, crystn. (-78°C, 6 h); further crop on concn. of filtrate; elem. anal.;
参考文献
Inorganic Chemistry, , vol. 36, # 27 p. 6247 - 6250
