反应条件
1: 1.) Mg / 1.) ether, 2.) ether, reflux, 16 h 2: 1.) NaBH4, BF3-etherate, 2.) 3 N aq. NaOH, 3.) 30percent aq. H2O2 / 1.) THF, 20-25 deg C, 20-25 min, 3.) THF, 30-35 deg C, 2 h 3: 76 percent / phosphorus tribromide / 20 h / 55 - 60 °C 4: 66 percent / liquid ammonia / 6 h 5: 1.) lithium amide, hexamethylphosphorotriamide / 1.) 20 deg C, 1 h, 2.) 40-45 deg C, 10 h 6: sodium borohydride, ethylenediamine / nickel acetate / aq. ethanol View Scheme
参考文献
Kovalev, B. G.; Rastegaeva, V. M.
Journal of Organic Chemistry USSR (English Translation), 1982 , vol. 18, p. 44 - 47
Zhurnal Organicheskoi Khimii, 1982 , vol. 18, # 1 p. 53 - 56
