formic acid; [Ir(phenylpyridine(-1H))2(4,4′-di-tert-butyl-2,2′-bipyridine)](PF6); N-ethyl-N,N-diisopropylamine in acetonitrile T=20°C; 48 h; Irradiation; chemoselective reaction;

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1: silica gel; C26H51N2O2(1+)*BF4(1-) / dichloromethane / 15 h / 20 °C 2: formic acid; [Ir(phenylpyridine(-1H))2(4,4′-di-tert-butyl-2,2′-bipyridine)](PF6); N-ethyl-N,N-diisopropylamine / acetonitrile / 48 h / 20 °C / |Irradiation View Scheme

1: sodium tetrahydroborate / water; tetrahydrofuran / 20 °C 2: silica gel; C26H51N2O2(1+)*BF4(1-) / dichloromethane / 15 h / 20 °C 3: formic acid; [Ir(phenylpyridine(-1H))2(4,4′-di-tert-butyl-2,2′-bipyridine)](PF6); N-ethyl-N,N-diisopropylamine / acetonitrile / 48 h / 20 °C / |Irradiation View Scheme