5-甲基-2-异丙基环己酮合成路线 （共 238 条）
反应条件
bei der elektrolytischen Reduktion;
参考文献
Schall; Kirst
Zeitschrift fuer Elektrochemie und Angewandte Physikalische Chemie, 1923 , vol. 29, p. 540
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Matsui; Shimizu
Ber. Schimmel, 1922 , p. 157
Chem. Zentralbl., 1922 , vol. 93, # IV p. 764
反应条件
1: Br2 / diethyl ether / 8 h / -10 °C
2: 8.7 percent / aq. NaOH / 6 h / 0 °C
View Scheme
参考文献
Utaka, Masanori; Matsushita, Seishiro; Takeda, Akira
Chemistry Letters, 1980 , p. 779 - 780
反应条件
natural kaolinitic clay in benzene
2 h; Heating;
参考文献
Ponde, Datta E.; Deshpande, Vishnu H.; Bulbule, Vivek J.; Sudalai, Ammugam; Gajare, Anil S.
Journal of Organic Chemistry, 1998 , vol. 63, # 4 p. 1058 - 1063
参考文献
Ciamician; Silber
Chemische Berichte, 1907 , vol. 40, p. 2416
Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti, 1907 , vol. <5>16 I, p. 835
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Ciamician; Silber
Annales de Chimie (Cachan, France), 1907 , vol. <8> 11, p. 435
反应条件
anhydrous potassium sulfate; potassium peroxomonosulphate; sulfuric acid
das hoeher schmelzende Lacton entsteht; solid 2.6-dimethyl-octanol-(3)-oic acid (8);
参考文献
Dilthey; Huchtemann
Journal fuer Praktische Chemie (Leipzig), 1940 , vol. <2> 154, p. 238,254
反应条件
oxygen; copper dichloride in acetic acid
T=80°C; Oxidation; 8 h;
参考文献
He, Liangyou; Horiuchi, C. Akira
Bulletin of the Chemical Society of Japan, 1999 , vol. 72, # 11 p. 2515 - 2521
反应条件
1: 1) lithium diisopropylamide / 1) THF, hexane, -78 deg C, 1 h, 2) THF, -78 deg C, 3 h
2: 58 percent / 30 percent aq. H2O2, MgSO4 / tetrahydrofuran / 4 h / Ambient temperature
View Scheme
参考文献
Hiroi, Kunio; Umemura, Masayuki
Tetrahedron Letters, 1992 , vol. 33, # 23 p. 3343 - 3346
反应条件
1: sodium; alcohol
2: 160 - 170 °C
View Scheme
参考文献
Beckmann
Journal fuer Praktische Chemie (Leipzig), 1897 , vol. <2> 55, p. 17
Chem. Zentralbl., 1887 , vol. 58, p. 1375,1461
反应条件
oxygen
bei der Einwirkung von Pflanzenenzymen;
参考文献
Ciamician; Ravenna
Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti, 1918 , vol. <5> 27 II, p. 296
Annales de Chimie (Cachan, France), 1919 , vol. <9> 12, p. 10
反应条件
Multi-step reaction with 3 steps 1: hydroxylamine hydrochloride; sodium carbonate / ethanol; water / 120 h / 25 °C2: sulfuric acid; N,N,N,N',N',N'-hexamethyl-butane-1,4-diammonium dimethylsulfate / methanol; water / 50 °C / Electrochemical reduction3: hydrogenchloride / diethyl ether / 0 °C
参考文献
Kulisch, Joern; Nieger, Martin; Stecker, Florian; Fischer, Andreas; Waldvogel, Siegfried R. Angewandte Chemie - International Edition, 2011 , vol. 50, # 24 p. 5564 - 5567
