5-甲基-2-异丙基环己酮合成路线 (共 238 条)
反应条件
1,2-cis-cyclohexaneanediol; oxygen T=25°C; pH 7.1, Acinetobacter NCIB 9871;
参考文献
Tetrahedron Asymmetry, , vol. 3, # 3 p. 379 - 382
反应条件
formic acid in water; acetone T=40°C; 20 h; Yield given. Yields of byproduct given;
参考文献
Angewandte Chemie, , vol. 98, # 12 p. 1093 - 1095
反应条件
formic acid in water; acetone T=40°C; 20 h;
参考文献
Angewandte Chemie, , vol. 98, # 12 p. 1093 - 1095
反应条件
hydrogen; palladium on activated charcoal in methanol 3 h; Ambient temperature; Yield given;
参考文献
Bulletin de la Societe Chimique de France, , vol. 134, # 8-9 p. 757 - 764
反应条件
silica gel; ozone T=-60 - -50°C; 2 h;
参考文献
Phytochemistry (Elsevier), , vol. 27, # 12 p. 3861 - 3870
反应条件
hydrogen; HRuCl(TBPC)2 in toluene T=65°C; P=7600 Torr; 26 h; asymmetric synthesis, var. chiral ruthenium catalyst, variation of time; MechanismProduct distribution;
参考文献
Tetrahedron, , vol. 44, # 5 p. 1409 - 1412
反应条件
1: LDA, TMEDA / tetrahydrofuran 2: aq. HCl / petroleum ether View Scheme
参考文献
Tetrahedron Letters, , vol. 28, # 44 p. 5313 - 5314
反应条件
3-chloro-benzenecarboperoxoic acid in chloroform 24 h; Heatingvar. reagents; Product distribution;
参考文献
Phytochemistry (Elsevier), , vol. 27, # 12 p. 3861 - 3870
反应条件
hydrogenchloride in Petroleum ether
参考文献
Tetrahedron Letters, , vol. 28, # 44 p. 5313 - 5314
反应条件
1: 88 percent / act. MnO2 / CH2Cl2 / 6 h / 20 °C 2: 7 percent / tetrahydrofuran / 1 h / -78 °C View Scheme
参考文献
Heterocycles, , vol. 52, # 3 p. 1029 - 1032