5-甲基-2-异丙基环己酮合成路线 (共 238 条)
反应条件
1: 91 percent / lithium (+/-)-2-(pyrrolidin-1-yl)methylpyrrolidide; DBU / tetrahydrofuran / 16 h / 20 °C 2: 88 percent / act. MnO2 / CH2Cl2 / 6 h / 20 °C 3: 7 percent / tetrahydrofuran / 1 h / -78 °C View Scheme
参考文献
Heterocycles, , vol. 52, # 3 p. 1029 - 1032
反应条件
1: hexane / -78 °C / Irradiation 2: HCOOH / H2O; acetone / 20 h / 40 °C View Scheme
参考文献
Angewandte Chemie, , vol. 98, # 12 p. 1093 - 1095
反应条件
1: 1) pyridine, 2) diglyme, 120 deg C 2: hexane / -78 °C / Irradiation 3: HCOOH / H2O; acetone / 20 h / 40 °C View Scheme
参考文献
Angewandte Chemie, , vol. 98, # 12 p. 1093 - 1095
反应条件
(-)-menthol; aluminum isopropoxide P=5 Torr;
参考文献
Angewandte Chemie, , vol. 39, p. 140
反应条件
1: 1.) n-BuLi / 1.) hexane, THF, r.t., 15 min; 2.) 45 min, -78 deg C, THF 2: 140 °C View Scheme
参考文献
Tetrahedron, , vol. 40, # 8 p. 1225 - 1234
反应条件
in ethanol; acetonitrile pH=4.6; 1 h; Inert atmosphereaq. buffer;
参考文献
European Journal of Organic Chemistry, , # 14 p. 2837 - 2854
参考文献
Bulletin of the Chemical Society of Japan, , vol. 37, p. 310,312
Memoirs of the College of Science, Kyoto Imperial University, , vol. <A> 22, p. 97,113
Chem.Abstr., , p. 403
反应条件
diethyl ether; alkyl magnesium halide Zerlegung der Magnesium-Verbindungen mit Salmiak und Essigsaeure (Herstellung der Enolform des Menthons, p-Menthen-(3)-ol-(3));
参考文献
Bulletin des Societes Chimiques Belges, , vol. 36, p. 106
Chem. Zentralbl., , vol. 98, # I p. 2998
反应条件
hydrogen; aluminum oxide; lithium hydroxide; copper T=250 - 270°C; P=11400 Torr; in the presence aliphatic nitriles; Product distribution;
参考文献
Chemistry of Natural Compounds, , vol. 17, p. 238 - 243
Khimiya Prirodnykh Soedinenii, , vol. 17, # 3 p. 312 - 317
反应条件
Nicotiana tabacum cells in water T=25°C; 96 h; biotransformation;
参考文献
Phytochemistry (Elsevier), , vol. 27, # 4 p. 1041 - 1044