3-甲基-3-丁烯-2-醇合成路线 （共 65 条）
反应条件
sulfuric acid beim Destillieren;
参考文献
DE632571 , ;
Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 23, p. 112
US2010076 , ;
FR763286 ;
Industrial and Engineering Chemistry, , vol. 33, p. 806
反应条件
(+-)-methylisopropenylcarbinol;
参考文献
Industrial and Engineering Chemistry, , vol. 33, p. 807
反应条件
nickel T=80°C; Hydrogenation.unter Druck;
参考文献
Shell Devel. Co.
Patent: US2055437 , 1935 ;
反应条件
T=530°C; (+-)-methylisopropenylcarbinol;
参考文献
Shell Devel.Co.
Patent: US2011317 , 1933 ;
反应条件
tetrabutylammomium bromide; sodium hydrogencarbonate; palladium dichloride T=120°C; Heck coupling; 24 h;
参考文献
Bouquillon, Sandrine; Ganchegui, Benjamin; Estrine, Boris; Henin, Francoise; Muzart, Jacques
Journal of Organometallic Chemistry, 2001 , vol. 634, # 2 p. 153 - 156
反应条件
tetrabutylammomium bromide; sodium hydrogencarbonate; palladium dichloride T=120°C; Heck coupling; 4 h;
参考文献
Bouquillon, Sandrine; Ganchegui, Benjamin; Estrine, Boris; Henin, Francoise; Muzart, Jacques
Journal of Organometallic Chemistry, 2001 , vol. 634, # 2 p. 153 - 156
反应条件
FcSO2-cyclo[-N(CH2CH=CHCH2N(Ts))2CH2CH=CHCH2-]Pd(O) in ethanol T=20°C; Heck arylation; 4.25 h; Product distribution; Further Variations:CatalystsSolventsTemperaturesreactant ratio, reaction times;
参考文献
Journal of Organometallic Chemistry, , vol. 690, # 16 p. 3822 - 3826
反应条件
1: 1.) n-BuLi, TMEDA / 1.) hexane, -78 deg C 2: 66 percent Chromat. / (PPh3)4Pd / toluene; triethylamine / 20 h / 65 °C / Other catalyst: Pd(OAc)2+PPh3, solvent: dioxane, Et3N+THF, temperature; 70 and 100 deg C. Object: isomeric purity. View Scheme
参考文献
Carpita, Adriano; Bonaccorsi, Fabrizio; Rossi, Renzo
Tetrahedron Letters, 1984 , vol. 25, # 45 p. 5193 - 5196
反应条件
1: 1.) n-BuLi, TMEDA / 1.) hexane, -78 deg C 2: 79 percent Chromat. / (PPh3)4Pd / toluene; triethylamine / 18 h / 65 °C View Scheme
参考文献
Tetrahedron Letters, , vol. 25, # 45 p. 5193 - 5196
反应条件
1: Py 2: (isomerization) View Scheme
参考文献
Lewis,E.S. et al.
Journal of the American Chemical Society, 1968 , vol. 90, p. 662 - 668
