3-甲基-3-丁烯-2-醇合成路线 （共 65 条）
反应条件
n-butyllithium; N,N,N',N,-tetramethylethylenediamine 1.) hexane, -78 deg C; Yield given. Multistep reaction;
参考文献
Carpita, Adriano; Bonaccorsi, Fabrizio; Rossi, Renzo
Tetrahedron Letters, 1984 , vol. 25, # 45 p. 5193 - 5196
反应条件
titanium(IV) isopropylate; 4 A molecular sieve; 3-hydroperoxy-2,3-dimethyl-2-butanol in chloroform-d1 T=20°C; 1 h; Yield given;
参考文献
Adam, Waldemar; Peters, Karl; Renz, Michael
Journal of Organic Chemistry, 1997 , vol. 62, # 10 p. 3183 - 3189
参考文献
Carpita, Adriano; Bonaccorsi, Fabrizio; Rossi, Renzo
Tetrahedron Letters, 1984 , vol. 25, # 45 p. 5193 - 5196
反应条件
1: trimethyl-sulfonium iodide With n-butyllithium in tetrahydrofuran; hexane
T=-10°C; 0.5 h;
2: cis–2,3–butene oxide in tetrahydrofuran; hexane
T=-10 - 20°C; Further stages.;
参考文献
Alcaraz, Lilian; Cridland, Andrew; Kinchin, Elizabeth
Organic Letters, 2001 , vol. 3, # 25 p. 4051 - 4053
反应条件
in diethyl ether
T=0°C; 1 h;
参考文献
Rickerby, Jenny; Vallet, Martial; Bernardinelli, Gerald; Viton, Florian; Kuendig, E. Peter
Chemistry - A European Journal, 2007 , vol. 13, # 12 p. 3354 - 3368
反应条件
magnesium bromide in N,N-dimethyl-formamide
T=130°C; 0.5 h;
参考文献
Mel'nik; Khvatova; Moskvichev; Srednev; Egorova
Petroleum Chemistry, 2003 , vol. 43, # 3 p. 167 - 169
反应条件
1: With 5,15,10,20-tetraphenylporphyrin in chloroform
0.0833333 h;
2: With sodium sulfite in water
T=20°C;
参考文献
Levesque, Francois; Seeberger, Peter H.
Organic Letters, 2011 , vol. 13, # 19 p. 5008 - 5011
反应条件
ethanol; magnesium oxide; zinc oxide
T=400°C;
参考文献
Ballard et al.
Adv. Catalysis, 1957 , vol. 9, p. 754,759
反应条件
lithium iodide in tetrahydrofuran; diethyl ether
T=50°C; Yield given;
参考文献
Concellon, Jose M.; Llavona, Lujan; Bernad, Pablo L. Jr.
Tetrahedron, 1995 , vol. 51, # 19 p. 5573 - 5584
反应条件
water; calcium carbonate
T=70°C; (+-)-methylisopropenylcarbinol;
参考文献
Shell Devel.Co.
Patent: US2072015 , 1932 ;
Full Text Show Details
Tischtschenko
Zhurnal Obshchei Khimii, 1936 , vol. 6, p. 1551
Chem. Zentralbl., 1937 , vol. 108, # I p. 3785
